3,5-Dioxa-2,10-disilaundec-7-ene, 2,2,10-trimethyl-4-methylene-9-(1-methylethyl)-10-phenyl-, (7Z)-

Base Information

Chemical Name:3,5-Dioxa-2,10-disilaundec-7-ene, 2,2,10-trimethyl-4-methylene-9-(1-methylethyl)-10-phenyl-, (7Z)-
CAS No.:679410-11-8
Molecular Formula:C₂₀H₃₄O₂Si₂
Molecular Weight:362.66
Hs Code.:

Synonyms:

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Chemical Property of 3,5-Dioxa-2,10-disilaundec-7-ene, 2,2,10-trimethyl-4-methylene-9-(1-methylethyl)-10-phenyl-, (7Z)-

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Technology Process of 3,5-Dioxa-2,10-disilaundec-7-ene, 2,2,10-trimethyl-4-methylene-9-(1-methylethyl)-10-phenyl-, (7Z)-

There total 7 articles about 3,5-Dioxa-2,10-disilaundec-7-ene, 2,2,10-trimethyl-4-methylene-9-(1-methylethyl)-10-phenyl-, (7Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 679410-24-3
4-dimethyl(phenyl)silyl-5-methylhex-2-yn-1-ol

: 679410-11-8
{[(Z)-1-Isopropyl-4-(1-trimethylsilanyloxy-vinyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 80 percent / DMAP; Et₃N / diethyl ether / 16 h / 20 °C

2.1: 68 percent / quinoline; H₂ / Pd/BaSO₄ / methanol / 72 h / 20 °C

3.1: LDA / tetrahydrofuran / 1 h / -78 °C

3.2: tetrahydrofuran / 2 h / -78 °C

With quinoline; dmap; hydrogen; triethylamine; lithium diisopropyl amide; Pd-BaSO₄; In tetrahydrofuran; methanol; diethyl ether; 2.1: Lindlar hydrogenation;
DOI:10.1039/b305881f

Reference yield:

: 90701-59-0
1,1-Dibromo-4-methyl-1-pentene

: 679410-11-8
{[(Z)-1-Isopropyl-4-(1-trimethylsilanyloxy-vinyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Guidance literature:: Multi-step reaction with 7 steps

1.1: n-Buli / hexane; diethyl ether

1.2: 78 percent / hexane; diethyl ether

2.1: tert-BuLi; TMEDA / hexane; tetrahydrofuran

2.2: 60 percent / hexane; tetrahydrofuran

3.1: 93 percent / aq. AgNO₃; KCN / ethanol / 20 °C

4.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 - -20 °C

4.2: 58 percent / tetrahydrofuran; hexane / 0.25 h / -78 °C

5.1: 80 percent / DMAP; Et₃N / diethyl ether / 16 h / 20 °C

6.1: 68 percent / quinoline; H₂ / Pd/BaSO₄ / methanol / 72 h / 20 °C

7.1: LDA / tetrahydrofuran / 1 h / -78 °C

7.2: tetrahydrofuran / 2 h / -78 °C

With quinoline; dmap; potassium cyanide; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; tert.-butyl lithium; silver nitrate; triethylamine; lithium diisopropyl amide; Pd-BaSO₄; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; 6.1: Lindlar hydrogenation;
DOI:10.1039/b305881f

Reference yield:

: 590-86-3
isovaleraldehyde

: 679410-11-8
{[(Z)-1-Isopropyl-4-(1-trimethylsilanyloxy-vinyloxy)-but-2-enyl]-dimethyl-silanyl}-benzene

Guidance literature:: Multi-step reaction with 8 steps

1.1: PPh₃ / CH₂Cl₂ / 0.67 h / -10 °C

1.2: 3.1 g / CH₂Cl₂

2.1: n-Buli / hexane; diethyl ether

2.2: 78 percent / hexane; diethyl ether

3.1: tert-BuLi; TMEDA / hexane; tetrahydrofuran

3.2: 60 percent / hexane; tetrahydrofuran

4.1: 93 percent / aq. AgNO₃; KCN / ethanol / 20 °C

5.1: n-BuLi / tetrahydrofuran; hexane / 1 h / -78 - -20 °C

5.2: 58 percent / tetrahydrofuran; hexane / 0.25 h / -78 °C

6.1: 80 percent / DMAP; Et₃N / diethyl ether / 16 h / 20 °C

7.1: 68 percent / quinoline; H₂ / Pd/BaSO₄ / methanol / 72 h / 20 °C

8.1: LDA / tetrahydrofuran / 1 h / -78 °C

8.2: tetrahydrofuran / 2 h / -78 °C

With quinoline; dmap; potassium cyanide; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; tert.-butyl lithium; silver nitrate; triethylamine; triphenylphosphine; lithium diisopropyl amide; Pd-BaSO₄; In tetrahydrofuran; methanol; diethyl ether; ethanol; hexane; dichloromethane; 7.1: Lindlar hydrogenation;
DOI:10.1039/b305881f