Furan, 3-methyl-2-(3-methyl-2-butenyl)-

Base Information

• Chemical Name: Furan, 3-methyl-2-(3-methyl-2-butenyl)-
• CAS No.: 15186-51-3
• Molecular Formula: C10H14 O
• Molecular Weight: 150.221
• Hs Code.: 2932190090
• UNII: PNC9VDU98G
• DSSTox Substance ID: DTXSID9065865
• Nikkaji Number: J14.082A
• Wikipedia: Rosefuran
• Wikidata: Q7368190
• Mol file: 15186-51-3.mol

Synonyms:rosefuran;15186-51-3;3-methyl-2-(3-methylbut-2-enyl)furan;Furan, 3-methyl-2-(3-methyl-2-butenyl)-;3-Methyl-2-(3-methylbut-2-enyl)-furan;.alpha.-Naginatene;UNII-PNC9VDU98G;PNC9VDU98G;Furan, 3-methyl-2-(3-methyl-2-buten-1-yl)-;3-METHYL-2(3-METHYLBUT-2-EN-1-YL)FURAN;(methylbutenyl)-methylfuran,2-(3-methyl-2-butenyl)-3-methylfuran;2-(3-methyl-2-butenyl)-3-methylfuran;.GAMMA.-CLAUSENANE;SCHEMBL3503787;DTXSID9065865;FEMA NO. 4174;2-(3'-methyl-2'-butenyl)-3-methylfuran;3-Methyl-2-(3-methyl-but-2-enyl)-furan;2(3-METHYL-2-BUTENYL)-3-METHYLFURAN;3-METHYL-2-(3-METHYL-2-BUTENYL)FURAN;Q7368190;3-METHYL-2(3-METHYLBUT-2-EN-1-YL)FURAN [FHFI]

Chemical Property of Furan, 3-methyl-2-(3-methyl-2-butenyl)-

Chemical Property:

• Vapor Pressure: 0.608mmHg at 25°C
• Boiling Point: 194.7°Cat760mmHg
• Flash Point: 62.6°C
• PSA: 13.14000
• Density: 0.914g/cm³
• LogP: 3.09670
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 150.104465066
• Heavy Atom Count: 11
• Complexity: 145

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=C(OC=C1)CC=C(C)C

Technology Process of Furan, 3-methyl-2-(3-methyl-2-butenyl)-

There total 55 articles about Furan, 3-methyl-2-(3-methyl-2-butenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

5-Oxogeraniol (130817-55-9) → 3-methyl-2-(3-methylbut-2-enyl)furan (15186-51-3)

Guidance literature:

With formic acid; In chloroform-d1; at 55 ℃; for 168h;

Reference yield: 97.0%

iodo(2-(3-methylfur-2-yl)ethyl)triphenylphosphorane + acetone (67-64-1) → 3-methyl-2-(3-methylbut-2-enyl)furan (15186-51-3)

Guidance literature:

With 18-crown-6 ether; potassium tert-butylate; In tetrahydrofuran; at 0 - 20 ℃; for 16h; Inert atmosphere;

DOI:10.1002/anie.202015232

Reference yield: 91.0%

(2Z)-3,7-dimethylocta-2,6-dien-4-yn-1-ol (149694-46-2) → 3-methyl-2-(3-methylbut-2-enyl)furan (15186-51-3)

Guidance literature:

With [Au{μ(P,N)-1’-(diphenylphosphanyl)-1-cyanoferrocene}]₂(bis(trifluoromethanesulfonyl)imide)₂; In chloroform; at 60 ℃; for 2h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1002/chem.201502968

upstream raw materials:

3-methylfuran

prenyl bromide

3-chloro-3-methyl-1-butene

trifluoroacetate de methyl-3 butene-2 ol-2

Downstream raw materials:

(6E,10E)-2,6,10-Trimethyl-12-(3-methyl-2-furyl)-8-(4-methylphenylsulfonyl)-2,6,10-dodecatrien

rosefuran epoxide