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67-64-1

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67-64-1 Usage

Safety Profile

Moderately toxic by various routes.A skin and severe eye irritant. Human systemic effects byinhalation: changes in EEG, changes in carbohydratemetabolism, nasal effects, conjunctiva irritation, respiratorysystem effects, nausea and vomiting, and muscl
InChI:InChI=1/C3H6O/c1-3(2)4/h1-2H3

67-64-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name acetone

1.2 Other means of identification

Product number -
Other names Dimethylketal

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Volatile organic compounds
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:67-64-1 SDS

67-64-1Synthetic route

isopropyl alcohol
67-63-0

isopropyl alcohol

acetone
67-64-1

acetone

Conditions
ConditionsYield
With trans-4L1(O)2>ClO4 In acetonitrile at 25℃; for 7h; stoicheiometric oxidation ( electrochemical oxidation in a non-aqueous medium (acetonitrile), an Ag-AgNO3 reference electrode;100%
With C19H20N3O2Ru(2+)*2F6P(1-) In aq. buffer at 24.84℃; for 1h; pH=1.8; Thermodynamic data; Activation energy; Reagent/catalyst;100%
With tert-butylethylene; C32H52ClIrP2; sodium t-butanolate at 200℃; for 2h; Catalytic behavior; Reagent/catalyst; Inert atmosphere; Glovebox;100%
pyridine
110-86-1

pyridine

tert-butylsulfinyl chloride
31562-43-3

tert-butylsulfinyl chloride

A

pyridine hydrochloride
628-13-7

pyridine hydrochloride

B

acetone
67-64-1

acetone

C

pyridinium tert-butylsulfonate

pyridinium tert-butylsulfonate

D

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With tert.-butylhydroperoxide In chloroform at 20℃; for 2h; Further byproducts given;A 100%
B 20%
C 40%
D 55%
2,3-dimethyl-2,3-butane diol
76-09-5

2,3-dimethyl-2,3-butane diol

acetone
67-64-1

acetone

Conditions
ConditionsYield
With N-Bromosuccinimide; water; potassium carbonate; triphenylbismuthane In acetonitrile for 2h;100%
With tert.-butylhydroperoxide; bis(acetylacetonato)dioxidomolybdenum(VI) In chlorobenzene at 60℃; for 24h;99%
With tert.-butylhydroperoxide; chromium tetra(tert-butoxide) In benzene at 20℃; for 24h;90%
5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione
3968-30-7

5-cyclopentylidene-2,2-dimethyl-1,3-dioxane-4,6-dione

A

butatriene
2873-50-9

butatriene

B

ethene
74-85-1

ethene

C

carbon dioxide
124-38-9

carbon dioxide

D

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

E

acetone
67-64-1

acetone

F

benzene
71-43-2

benzene

Conditions
ConditionsYield
With variation of temp. at 550℃; Product distribution;A 4%
B 11.9%
C 100%
D 39.2%
E 101.9 %
F 3.3%
cyclohexane
110-82-7

cyclohexane

perpentene-4 oate de tertiobutyle
84210-61-7

perpentene-4 oate de tertiobutyle

A

cyclohexylcyclohexane
92-51-3

cyclohexylcyclohexane

B

butylcyclohexane
1678-93-9

butylcyclohexane

C

cyclohexyl-5 pentanolide-4
96009-79-9

cyclohexyl-5 pentanolide-4

D

acetone
67-64-1

acetone

E

5-methyl-dihydro-furan-2-one
108-29-2

5-methyl-dihydro-furan-2-one

F

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 120℃; for 4h; Product distribution; Mechanism; different ratios of reactant, reactants, reaction times and temperatures;A 5%
B 5%
C 35%
D n/a
E 1%
F 100%
cyclohexane
110-82-7

cyclohexane

1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical
80037-90-7

1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical

2-(t-butylazo)prop-2-yl hydroperoxide
37421-16-2

2-(t-butylazo)prop-2-yl hydroperoxide

A

2-cyclohexyloxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole
89482-40-6

2-cyclohexyloxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole

B

2-tert-butoxy-1,1,3,3-tetramethylisoindoline
93524-81-3

2-tert-butoxy-1,1,3,3-tetramethylisoindoline

C

acetone
67-64-1

acetone

D

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
at 70℃; for 17h; Mechanism; Rate constant; Thermodynamic data; var. of nitroxide, solvent, temp., EA, ΔH(excit.), ΔS(excit.);A 96%
B 82%
C 100%
D 15%
2-(octylsulfonyl)ethyl tert-butyl peroxide
83073-73-8

2-(octylsulfonyl)ethyl tert-butyl peroxide

A

methane
34557-54-5

methane

B

2-hydroxyethyl octyl sulfone
20466-47-1

2-hydroxyethyl octyl sulfone

C

acetone
67-64-1

acetone

D

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
In various solvent(s) at 145℃; Rate constant; Thermodynamic data; E(act.);A n/a
B 100%
C n/a
D n/a
H-Dmt-Gly-Gly-Ala-OH trifluoroacetate salt
120711-57-1

H-Dmt-Gly-Gly-Ala-OH trifluoroacetate salt

A

H-Cys-Gly-Gly-Ala-OH
120711-58-2

H-Cys-Gly-Gly-Ala-OH

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
In ethanol; water Heating;A 100%
B n/a
Isopropenyl acetate
108-22-5

Isopropenyl acetate

phenol
108-95-2

phenol

A

acetone
67-64-1

acetone

B

Phenyl acetate
122-79-2

Phenyl acetate

Conditions
ConditionsYield
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h;A n/a
B 100%
With potassium carbonate; Aliquat 336 In neat (no solvent) at 70℃; for 0.5h; Product distribution;A n/a
B 100%
2,2-dimethyl-5-(phenyl-λ3-iodaneylidene)-1,3-dioxane-4,6-dione
34107-52-3

2,2-dimethyl-5-(phenyl-λ3-iodaneylidene)-1,3-dioxane-4,6-dione

A

cycl-isopropylidene malonate
2033-24-1

cycl-isopropylidene malonate

B

iodobenzene
591-50-4

iodobenzene

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
With dirhodium tetraacetate In dichloromethane at 20℃; Product distribution;A 33%
B 100%
C 5%
dimethyl(2,2'-bipyridyl)nickel(II)

dimethyl(2,2'-bipyridyl)nickel(II)

A

NiCH3(N(CO)2C6H4)(P(C2H5)3)2
67552-35-6, 79390-59-3, 79042-98-1

NiCH3(N(CO)2C6H4)(P(C2H5)3)2

B

Ni(CO)2(2,2'-bipyridine)
14917-14-7

Ni(CO)2(2,2'-bipyridine)

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
In benzene-d6 40°C, 72 h;A 100%
B n/a
C 33%
CpRe(CO)2(COCH3)(CH3)

CpRe(CO)2(COCH3)(CH3)

triphenylphosphine
603-35-0

triphenylphosphine

A

(η5-C5H5)Re(CO)2(PPh3)

(η5-C5H5)Re(CO)2(PPh3)

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
In 1,4-dioxane; benzene-d6 Kinetics; 100°C (10.25 h);A 100%
B 97%
In benzene-d6 Irradiation (UV/VIS);A 55%
B n/a
tetrachloromethane
56-23-5

tetrachloromethane

CpRe(CO)2(COCH3)(CH3)

CpRe(CO)2(COCH3)(CH3)

A

tricarbonylcyclopentadienylrhenium

tricarbonylcyclopentadienylrhenium

B

acetyl chloride
75-36-5

acetyl chloride

C

dimethylglyoxal
431-03-8

dimethylglyoxal

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With CO In dichloromethane-d2 Irradiation (UV/VIS); 355-385 nm; 20 atm CO;;A 100%
B n/a
C n/a
D n/a
CpRe(CO)2(COCH3)(CH3)

CpRe(CO)2(COCH3)(CH3)

3,4-hexanedione
4437-51-8

3,4-hexanedione

A

tricarbonylcyclopentadienylrhenium

tricarbonylcyclopentadienylrhenium

B

2,3-Pentanedione
600-14-6

2,3-Pentanedione

C

dimethylglyoxal
431-03-8

dimethylglyoxal

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With CO In benzene-d6 Irradiation (UV/VIS); 355-385 nm;;A 100%
B 68%
C 34%
D 10%
CpRe(CO)2(CH3)2

CpRe(CO)2(CH3)2

A

tricarbonylcyclopentadienylrhenium

tricarbonylcyclopentadienylrhenium

B

dimethylglyoxal
431-03-8

dimethylglyoxal

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
With CO In dichloromethane-d2 Irradiation (UV/VIS); 20 atm CO;;A 100%
B 79%
C 5%
CpRe(CO)2(COCH3)(CH3)

CpRe(CO)2(COCH3)(CH3)

A

tricarbonylcyclopentadienylrhenium

tricarbonylcyclopentadienylrhenium

B

dimethylglyoxal
431-03-8

dimethylglyoxal

C

acetone
67-64-1

acetone

Conditions
ConditionsYield
With carbon monoxide In dichloromethane-d2 Irradiation (UV/VIS); Irradiation of complex at 350-380 nm under 20 atm of CO in CD2Cl2 at 6-8°C;;A 100%
B 80%
C 8%
With CO In 1,4-dioxane; dichloromethane-d2 Irradiation (UV/VIS); ca. 20 atm CO; 355-385 nm light, 22 min.;A 100%
B 78%
C 6%
(3-(tert-butylperoxy)pentane-3yl)benzene

(3-(tert-butylperoxy)pentane-3yl)benzene

A

1-phenyl-propan-1-one
93-55-0

1-phenyl-propan-1-one

B

acetone
67-64-1

acetone

C

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
With air In [D3]acetonitrile at 22℃; for 1h; UV-irradiation; Inert atmosphere;A 100%
B 41.9%
C 25.9%
4-amino-3-penten-2-one
1118-66-7

4-amino-3-penten-2-one

acetone
67-64-1

acetone

Conditions
ConditionsYield
at 250℃; for 0.666667h; Heating; Inert atmosphere;99.76%
2,5-dimethyl-2,5-hexanediol
110-03-2

2,5-dimethyl-2,5-hexanediol

A

Succinimide
123-56-8

Succinimide

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With N-iodo-succinimide In benzene for 0.916667h; Product distribution; Mechanism; Irradiation; varying reaction time;A 88%
B 99%
acetophenone
98-86-2

acetophenone

isopropyl alcohol
67-63-0

isopropyl alcohol

A

(S)-1-phenylethanol
1445-91-6

(S)-1-phenylethanol

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With cis-[Ru(PPh2)(CH2)5PPh2(ampi)Cl2]; potassium hydroxide at 80℃; for 0.5h; Reagent/catalyst; Concentration; Schlenk technique;A 99%
B n/a
Stage #1: isopropyl alcohol With dichloro(1,5-cyclooctadiene)ruthenium(II); (R)-(6-methoxyquinolin-4-yl)((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methanamine at 20℃; for 0.5h; Inert atmosphere;
Stage #2: With potassium hydroxide for 0.5h; Inert atmosphere;
Stage #3: acetophenone at 0℃; for 96h; Inert atmosphere; enantioselective reaction;
A 83%
B n/a
With potassium hydroxide; oxalyl (1R,2R)-N,N'-bis[2-(amino)cyclohexyl]diamide; tris(triphenylphosphine)ruthenium(II) chloride at 20℃; for 24h; Product distribution; Further Variations:; Reagents;
9-fluorenone
486-25-9

9-fluorenone

isopropyl alcohol
67-63-0

isopropyl alcohol

A

9-Fluorenol
1689-64-1

9-Fluorenol

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With [RuCl2(triphenylphosphine)((6-((3,5-dimethyl-pyrazol-1-yl)pyridin-2-yl)methylene)-p-tolyl-amine)]*0.5Et2O; potassium isopropoxide at 82℃; under 750.075 Torr; for 5.16667h; Inert atmosphere;A 99%
B n/a
With sodium hydroxide; RuCl2(PPh3)(iBu-BTP) at 82℃; under 750.075 Torr; for 9h;A 97 % Chromat.
B n/a
(H2O)5CrC(CH3)2OH(2+)

(H2O)5CrC(CH3)2OH(2+)

A

chromium (III) ion

chromium (III) ion

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With Fe(3+) In water; isopropyl alcohol Kinetics; byproducts: H(1+); excess of Fe(3+) in 1 M aq. i-PrOH at 24.8°C under N2 by controlled ionic strength;A n/a
B 99%
ethyl 2-benzoyl-6-methylhept-5-enoate

ethyl 2-benzoyl-6-methylhept-5-enoate

A

ethyl 2-phenylcyclopent-2-ene-1-carboxylate

ethyl 2-phenylcyclopent-2-ene-1-carboxylate

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With gold(III) chloride In 1,2-dichloro-ethane at 25℃; Reagent/catalyst; Solvent; Sealed tube;A 99%
B n/a
With N-iodo-succinimide In 1,2-dichloro-ethane at 20℃; for 24h; Reagent/catalyst;A 66%
B n/a
4-fluoro-2-(5-methylhex-4-en-1-yl)benzaldehyde

4-fluoro-2-(5-methylhex-4-en-1-yl)benzaldehyde

A

3-fluoro-6,7-dihydro-5H-benzo[7]annulene

3-fluoro-6,7-dihydro-5H-benzo[7]annulene

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With gold(III) chloride In 1,2-dichloro-ethane at 25℃; Sealed tube;A 99%
B n/a
Cumene hydroperoxide
80-15-9

Cumene hydroperoxide

A

acetone
67-64-1

acetone

B

phenol
108-95-2

phenol

Conditions
ConditionsYield
With iron(III) perchlorate In acetonitrile Product distribution; var. act.: CuClO4; var. solv.: CH2Cl2, toluene; var. conc.; determination of half life;A 98.9%
B 96.3%
With N-Phenyl-2-naphthylamine; cobalt(II) phthalocyanine In decalin at 40℃; Rate constant; Kinetics; var. temperatures, var. catalysts, var. solvents, without NA;
In chlorobenzene at 75℃; Kinetics; various phosphites;
isopropyl alcohol
67-63-0

isopropyl alcohol

A

propene
187737-37-7

propene

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
6xSAlH (sulfated alumina) at 246.85℃; Product distribution; Further Variations:; Catalysts; atmospheric pressure;A 98.4%
B 1.6%
bismuth molybdate; bismuth molybdate at 190℃; Product distribution; with Bi2Mo2O9 (β-phase) catalyst;A 12%
B 88%
With cobalt ferrite; oxygen at 299.84℃; for 3h; Autoclave;A 52%
B 40%
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

2,2'-azinobis-(3-ethyl-2,3-dihydrobenzothiazole-6-sulphonate) diammonium salt
30931-67-0

2,2'-azinobis-(3-ethyl-2,3-dihydrobenzothiazole-6-sulphonate) diammonium salt

A

methanol
67-56-1

methanol

B

formaldehyd
50-00-0

formaldehyd

C

C18H18N4O6S4(1+)*2H3N

C18H18N4O6S4(1+)*2H3N

D

acetone
67-64-1

acetone

E

tert-butyl alcohol
75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
Fe(III)T4MPyP In water at 30℃; Rate constant; Kinetics; Mechanism; the catalyst Fe(III)T4MPyP is 5,10,15,20-tetra(N-methyl-4-pyridyl)-porphyrinatoiron(III) pentachloride; pH 9.2; investigation of the dependence of velocity constant on ionic strength, pH and t-butyl hydroperoxide concentration;A 3%
B n/a
C 72%
D 4%
E 98%
(4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine
87051-12-5

(4aRS,7aRS)-4a,7a-dihydro-3,3-dimethyl-6,7a-diphenyl-7H-cyclopenta<1,2-e><1,2,4>trioxine

(1RS,2RS)-1,4-diphenylcyclopent-3-en-1,2 diol
114390-60-2

(1RS,2RS)-1,4-diphenylcyclopent-3-en-1,2 diol

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With acetic acid; zinc at 16℃; for 0.333333h;A 98%
B n/a
para-chloroacetophenone
99-91-2

para-chloroacetophenone

isopropyl alcohol
67-63-0

isopropyl alcohol

A

1-(p-chlorophenyl)ethyl alcohol
3391-10-4

1-(p-chlorophenyl)ethyl alcohol

B

acetone
67-64-1

acetone

Conditions
ConditionsYield
With C58H49ClN5P2Ru(1+)*Cl(1-); potassium isopropoxide at 82℃; for 0.00555556h; Inert atmosphere;A 98%
B n/a
With sodium hydroxide; RuCl2(PPh3)(iBu-BTP) at 82℃; under 750.075 Torr; for 30h;A 89 % Chromat.
B n/a
With [RuCl2(triphenylphosphine)((6-((3,5-dimethyl-pyrazol-1-yl)pyridin-2-yl)methylene)-p-tolyl-amine)]*0.5Et2O; potassium isopropoxide at 82℃; under 750.075 Torr; for 1.16667h; Inert atmosphere;A 98 %Chromat.
B n/a
NiMe2(PEt3)2

NiMe2(PEt3)2

A

(CO)2Ni(P(C2H5)3)2
16787-33-0

(CO)2Ni(P(C2H5)3)2

B

acetaldehyde
75-07-0

acetaldehyde

C

dimethylglyoxal
431-03-8

dimethylglyoxal

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
With carbon monoxide In diethyl ether Et2O soln. of Ni complex stirred under CO at -78°C for 0.2 h, warmed to room temp.; drying up; GLC anal.;A n/a
B 0%
C 0%
D 98%
styrene oxide
96-09-3

styrene oxide

acetone
67-64-1

acetone

2,2-dimethyl-4-phenyl-1,3-dioxolane
52129-03-0

2,2-dimethyl-4-phenyl-1,3-dioxolane

Conditions
ConditionsYield
With FeOx-pillared bentonite at 30℃; for 0.0833333h; Reagent/catalyst; Time; Temperature; Solvent;100%
erbium(III) triflate at 20℃; for 0.5h;99%
With trichloro(trifluoromethanesulfonato)titanium(IV); n-tetrabutylammonium hydroxide In water for 0.166667h; Ambient temperature;98%
piperonal
120-57-0

piperonal

acetone
67-64-1

acetone

(1E,4E)-1,5-bis(benzo[d][1,3]dioxol-5-yl)penta-1,4-dien-3-one
108439-88-9

(1E,4E)-1,5-bis(benzo[d][1,3]dioxol-5-yl)penta-1,4-dien-3-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol for 0.00833333h; Irradiation;100%
With sodium hydroxide In ethanol; water at 20℃;85%
With sodium hydroxide In ethanol; water at 20℃; Aldol Addition;79%
4-nitrobenzaldehdye
555-16-8

4-nitrobenzaldehdye

acetone
67-64-1

acetone

1-(4-nitrophenyl)-1-hydroxy-3-butanone
88958-64-9, 88958-65-0, 97600-21-0, 57548-40-0

1-(4-nitrophenyl)-1-hydroxy-3-butanone

Conditions
ConditionsYield
With Zn(2+)-(TyrOEt)2 In water at 40℃; for 24h; pH 7;100%
With sodium hydroxide at 25℃; for 0.166667h;100%
With Fe(OH)3/Fe3O4 at 50℃; for 3h;99%
6-Chloropurine riboside
2004-06-0

6-Chloropurine riboside

acetone
67-64-1

acetone

6-chloro-9-(2,3-O-isopropylidene-β-D-ribofuranosyl)-9H-purine
39824-26-5

6-chloro-9-(2,3-O-isopropylidene-β-D-ribofuranosyl)-9H-purine

Conditions
ConditionsYield
With toluene-4-sulfonic acid at 20℃; for 3h;100%
In perchloric acid for 3h; Ambient temperature;94%
With perchloric acid at 25℃;94%
cyclopenta-1,3-diene
542-92-7

cyclopenta-1,3-diene

acetone
67-64-1

acetone

6,6'-dimethyl fulvene
2175-91-9

6,6'-dimethyl fulvene

Conditions
ConditionsYield
Stage #1: cyclopenta-1,3-diene; acetone With pyrrolidine In methanol at 20℃; Inert atmosphere;
Stage #2: With acetic acid In methanol for 0.15h;
100%
With pyrrolidine In methanol at -10 - 20℃; for 1h; Inert atmosphere;100%
With methylamine for 4.5h;92%
4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

acetone
67-64-1

acetone

(1E,4E)-1,5-bis(4-hydroxyphenyl)penta-1,4-dien-3-one
3654-49-7

(1E,4E)-1,5-bis(4-hydroxyphenyl)penta-1,4-dien-3-one

Conditions
ConditionsYield
With hydrogenchloride In tetrahydrofuran for 264h;100%
With hydrogenchloride; acetic acid at 25 - 30℃; for 2h; Heating;95%
With hydrogenchloride In acetic acid at 25 - 30℃; for 2h;95%
4-methoxy-benzaldehyde
123-11-5

4-methoxy-benzaldehyde

acetone
67-64-1

acetone

4-(p-methoxyphenyl)-3-butene-2-one
943-88-4

4-(p-methoxyphenyl)-3-butene-2-one

Conditions
ConditionsYield
With sodium hydroxide In water at 120℃; under 6750.68 Torr; Aldol condensation; Continuous flow;100%
With 1-n-butyl-3-methylimidazolim bromide; bovine serum albumin at 60℃; for 6h; Aldol Condensation; Green chemistry; Enzymatic reaction;98%
With sodium hydroxide for 72h; Ambient temperature;97%
pivalaldehyde
630-19-3

pivalaldehyde

acetone
67-64-1

acetone

4-hydroxy-2,2-dimethyl-6-heptanone
101713-95-5

4-hydroxy-2,2-dimethyl-6-heptanone

Conditions
ConditionsYield
With sodium hydroxide at 20℃;100%
Stage #1: acetone With sodium hydroxide In water at 20℃; Microfluidic conditions;
Stage #2: pivalaldehyde; acetone In water at 20℃; Microfluidic conditions;
100%
With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; for 0.583333h;47%
acetic acid hydrazide
1068-57-1

acetic acid hydrazide

acetone
67-64-1

acetone

acetic acid isopropylidenehydrazide
3742-63-0

acetic acid isopropylidenehydrazide

Conditions
ConditionsYield
In cyclohexane at 55℃; for 16h;100%
In hexane Reflux;93%
In hexane for 4h; Heating;91%
β-naphthaldehyde
66-99-9

β-naphthaldehyde

acetone
67-64-1

acetone

4-(2-naphtalenyl)-3-buten-2-one
75032-63-2

4-(2-naphtalenyl)-3-buten-2-one

Conditions
ConditionsYield
With potassium hydroxide In methanol; water at 20℃; for 0.5h;100%
With boehmite at 55℃; for 24h; Aldol Condensation; Green chemistry;55%
With sodium hydroxide
2,5-dimethoxybenzaldehyde
93-02-7

2,5-dimethoxybenzaldehyde

acetone
67-64-1

acetone

trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one
118709-30-1

trans-1-(2,5-dimethoxyphenyl)-2-buten-3-one

Conditions
ConditionsYield
With sodium hydroxide at 23℃; for 6.5h;100%
Stage #1: 2,5-dimethoxybenzaldehyde; acetone With L-proline In dimethyl sulfoxide at 20℃; for 48h;
Stage #2: With hydrogenchloride In water; dimethyl sulfoxide for 3h;
62.5%
With sodium hydroxide at 20℃; for 0.5h;53%
phenylacetylene
536-74-3

phenylacetylene

acetone
67-64-1

acetone

2-Methyl-4-phenyl-3-butyn-2-ol
1719-19-3

2-Methyl-4-phenyl-3-butyn-2-ol

Conditions
ConditionsYield
phosphazene base-P4-tert-butyl In hexane; dimethyl sulfoxide at 120℃; for 24h;100%
Stage #1: phenylacetylene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Inert atmosphere;
Stage #2: acetone In tetrahydrofuran; hexane at -78 - 20℃;
100%
With Nd(3+)*8Na(1+)*10C4H9O(1-)*HO(1-) In dimethyl sulfoxide at 30℃; for 24h; Catalytic behavior; Concentration; Solvent; Reagent/catalyst; Inert atmosphere;100%
aniline
62-53-3

aniline

acetone
67-64-1

acetone

N-(propan-2-ylidene)aniline
1124-52-3

N-(propan-2-ylidene)aniline

Conditions
ConditionsYield
With cis-(Cl,Cl)-[Re(p-NC6H4CH3)Cl2(py-2-COO)(PPh3)] at 70℃; for 24h; Inert atmosphere;100%
With microporous zeolite at 230℃; for 24h; Sealed tube; Autoclave;97%
sodium hydrogen sulfate; silica gel at 50 - 52℃; for 0.0333333h; microwave irradiation;75%
2-amino-benzenethiol
137-07-5

2-amino-benzenethiol

acetone
67-64-1

acetone

2,2-dimethyl-2,3-dihydro-benzothiazole
25111-89-1

2,2-dimethyl-2,3-dihydro-benzothiazole

Conditions
ConditionsYield
at 0℃; for 2h; gas/solid reaction;100%
Stage #1: 2-amino-benzenethiol; acetone In neat (no solvent) at 50℃; for 1h; Green chemistry;
Stage #2: With o-benzenedisulfonimide In neat (no solvent) at 50℃; for 48h; Green chemistry;
87%
With aluminum oxide at 20℃; for 0.5h;84%
4-dimethylamino-benzaldehyde
100-10-7

4-dimethylamino-benzaldehyde

acetone
67-64-1

acetone

4-p-dimethylaminophenyl-3-buten-2-one
5432-53-1

4-p-dimethylaminophenyl-3-buten-2-one

Conditions
ConditionsYield
With sodium hydroxide for 72h; Ambient temperature;100%
With water; potassium hydroxide at 20℃; for 0.2h;82%
With sodium hydroxide In water at 0 - 20℃; Aldol condensation;67.73%
1.3-propanedithiol
109-80-8

1.3-propanedithiol

acetone
67-64-1

acetone

2,2-dimethyl-1,3-dithiane
6007-22-3

2,2-dimethyl-1,3-dithiane

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 25℃;100%
With titanium tetrachloride79%
acid78%
propylene glycol
57-55-6

propylene glycol

acetone
67-64-1

acetone

2,2,4-trimethyl-1,3-dioxolane
1193-11-9, 116944-25-3

2,2,4-trimethyl-1,3-dioxolane

Conditions
ConditionsYield
With cyclohexane at 105℃; for 1h; Dean-Stark;100%
With Amberlyst 36 at 50℃; for 2h;75%
With 4 A molecular sieve; Amberlyst A 15 In tetrahydrofuran for 24h; Ambient temperature;35%
3,4-dimethylbenzaldehyde
5973-71-7

3,4-dimethylbenzaldehyde

acetone
67-64-1

acetone

(E)-4-(3,4-dimethylphenyl)but-3-en-2-one
97241-86-6

(E)-4-(3,4-dimethylphenyl)but-3-en-2-one

Conditions
ConditionsYield
With sodium hydroxide In water at 0 - 25℃; for 6h;100%
With sodium hydroxide
With sodium hydroxide In water at 25℃; for 12h;
2-nitrobenzenesulfonyl hydrazide
5906-99-0

2-nitrobenzenesulfonyl hydrazide

acetone
67-64-1

acetone

N-isopropylidene-N’-2-nitrobenzenesulfonyl hydrazine
6655-27-2

N-isopropylidene-N’-2-nitrobenzenesulfonyl hydrazine

Conditions
ConditionsYield
at 0℃; for 1h;100%
at 24℃; for 0.166667h; Inert atmosphere;95%
at 0 - 23℃;89%
acetone
67-64-1

acetone

glycerol
56-81-5

glycerol

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol
100-79-8

(R,S)-2,2-dimethyl-1,3-dioxolane-4-methanol

Conditions
ConditionsYield
With sulfuric acid at 40℃; Reagent/catalyst;100%
With toluene-4-sulfonic acid In hexane at 70℃; for 12h; Dean-Stark; Molecular sieve; Inert atmosphere;100%
Acidic conditions;100%
acetone
67-64-1

acetone

3,4-dichlorobenzaldehyde
6287-38-3

3,4-dichlorobenzaldehyde

(1E,4E)-1,5-bis(3,4-dichlorophenyl)penta-1,4-dien-3-one
30983-80-3

(1E,4E)-1,5-bis(3,4-dichlorophenyl)penta-1,4-dien-3-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 20℃; for 1h;100%
With sodium hydroxide In ethanol; water at 20℃; Aldol Addition;70%
With sodium hydroxide
With sodium hydroxide In ethanol
acetone
67-64-1

acetone

uridine
58-96-8

uridine

2',3'-O-isopropylideneuridine
362-43-6

2',3'-O-isopropylideneuridine

Conditions
ConditionsYield
With sulfuric acid at 20℃; for 1h;100%
Stage #1: acetone; uridine With sulfuric acid at 20℃; for 1h;
Stage #2: With triethylamine In acetone Product distribution / selectivity;
100%
With sulfuric acid at 20℃; for 1h;100%
acetone
67-64-1

acetone

ethylhydrazine carboxylate
4114-31-2

ethylhydrazine carboxylate

N'-isopropylidenehydrazinecarboxylic acid ethyl ester
6637-60-1

N'-isopropylidenehydrazinecarboxylic acid ethyl ester

Conditions
ConditionsYield
100%
With magnesium sulfate Reflux;100%
for 2h; Heating;98%
acetone
67-64-1

acetone

(2-2H)propan-2-(2H)ol
19214-95-0

(2-2H)propan-2-(2H)ol

Conditions
ConditionsYield
With lithium aluminium deuteride In diethylene glycol dimethyl ether at 0℃; for 1h; Inert atmosphere;100%
With pyrographite; platinum; deuterium at 25℃; under 1520 Torr; an mit Eisensalz;
With lithium aluminium deuteride
acetone
67-64-1

acetone

acetylmethanenitrolic acid
6868-83-3

acetylmethanenitrolic acid

Conditions
ConditionsYield
With dinitrogen tetraoxide In tetrachloromethane 1.) 0 deg C, 20 min, 2.) 20 deg C, 40 min;100%
With nitric acid
acetone
67-64-1

acetone

isopropyl alcohol
67-63-0

isopropyl alcohol

Conditions
ConditionsYield
With hydrogen; mer-Os(PPh3)3HBr(CO) In toluene at 150℃; under 51680 Torr; for 3h;100%
With hydrogen; sodium methylate; chromium(0) hexacarbonyl In methanol at 120℃; under 75006 Torr; for 3h;100%
With hydrogen; Ru((R,R)-cyP2N2)HCl In benzene-d6 at 20℃; under 2280.15 Torr; for 12h; Product distribution / selectivity; Alkaline conditions; Cooling with liquid nitrogen;100%
acetone
67-64-1

acetone

methyl α-D-lyxopyranoside
18449-76-8

methyl α-D-lyxopyranoside

methyl 2,3-O-isopropylidene-α-D-lyxopyranoside
60562-98-3

methyl 2,3-O-isopropylidene-α-D-lyxopyranoside

Conditions
ConditionsYield
With 4 A molecular sieve; amberlyst-15 (H form) at 23℃; for 4h;100%
With sulfuric acid; copper(II) sulfate for 24h; Ambient temperature;81%
With sulfuric acid
With phosphorus pentoxide
acetone
67-64-1

acetone

adenosine
58-61-7

adenosine

2',3'-isopropylidene adenosine
362-75-4

2',3'-isopropylidene adenosine

Conditions
ConditionsYield
With toluene-4-sulfonic acid; orthoformic acid triethyl ester at 20℃;100%
With p-toluenesulfonic acid monohydrate for 3h; Inert atmosphere;100%
With toluene-4-sulfonic acid at 20℃; for 1h; Inert atmosphere;99%
benzaldehyde
100-52-7

benzaldehyde

acetone
67-64-1

acetone

Conditions
ConditionsYield
With sodium hydroxide at 20℃;100%
Stage #1: acetone With sodium hydroxide In water at 20℃; Microfluidic conditions;
Stage #2: benzaldehyde; acetone In water at 20℃; Microfluidic conditions;
100%
With pyrrolidine; 4-nitro-phenol at 20℃; for 2.5h;99.4%