chloro(2,4,6-trimethylphenyl)mercury

Base Information

• Chemical Name: chloro(2,4,6-trimethylphenyl)mercury
• CAS No.: 20883-32-3
• Molecular Formula: C9H11ClHg
• Molecular Weight: 355.229
• Mol file: 20883-32-3.mol

Synonyms:

Chemical Property of chloro(2,4,6-trimethylphenyl)mercury

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloro(2,4,6-trimethylphenyl)mercury

There total 7 articles about chloro(2,4,6-trimethylphenyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

bis(2,4,6-trimethylphenyl)-zinc (73681-65-9) + mercury dichloride → 2,4,6-(CH3)3C6H2HgCl (20883-32-3)

Guidance literature:

In tetrahydrofuran; byproducts: ZnCl2; stirred under Ar;

Reference yield: 61.0%

{2,4,6-(CH3)3C6H2}2Hg (26562-17-4) → [(mercury)(mesityl)Cl]2HgCl2 + 2,4,6-(CH3)3C6H2HgCl (20883-32-3)

Guidance literature:

In chloroform; Irradiation (UV/VIS); Hg(mesityl)2 combined with CHCl3; irradiated at 510 nm for 1290 min; slowly concd. at ambient temp.; detd. by NMR;

DOI:10.1002/zaac.201100049

Reference yield:

2-mesitylmagnesium bromide (2633-66-1) → 2,4,6-(CH3)3C6H2HgCl (20883-32-3)

Guidance literature:

Multi-step reaction with 2 steps

1: dioxane / tetrahydrofuran

With dioxane; In tetrahydrofuran;

upstream raw materials:

cis-dichloro-((Me)(Ph₂)phosphine)(carbonyl)platinum(II)

{2,4,6-(CH3)3C6H2}2Hg

bis(2,4,6-trimethylphenyl)-zinc

benzyldichloroborane

Downstream raw materials:

1,2,3,5-Tetramethylbenzene

(2-Chlor-ethyl)-mesitylen

bis(2,4,6-trimethylphenyl)disulfide

Refernces