Technology Process of Bis(2,4,6-trimethylphenyl)mercury
There total 4 articles about Bis(2,4,6-trimethylphenyl)mercury which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
cesium carbonate;
In
isopropyl alcohol;
under Ar; i-PrOH added to mixt. of Hg acetate, B compd. and Cs2CO3; sealed; heated at 50-55°C (oil bath) for 12-20 h; cooled; solvent removed by rotary evapn.; extd. with toluene or toluene-THF; filtered; filtrate reduced to dryness by rotary evapn.; triturated with pentane; dried; recrystd. from THF-pentane; elem. anal.;
DOI:10.1016/j.jorganchem.2008.10.024
- Guidance literature:
-
In
tetrahydrofuran;
to suspn. of HgCl2 in THF added mesityllithium at room temp.; stirred for 10 h; volatiles removed in vacuo; residue extd. with benzene; extract filteredthrough frit; filtrate slowly concd.;
DOI:10.1002/zaac.201100049
