Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester

Base Information

Chemical Name:Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester
CAS No.:683246-09-5
Molecular Formula:C15H18O4
Molecular Weight:262.306
Hs Code.:

Synonyms:4-[3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]benzoic acid methyl ester;4-((E)-2-tert-butoxycarbonyl-vinyl)-benzoic acid methyl ester;methyl 4-((E)-2-(tert-butoxycarbonyl)vinyl)benzoate;methyl 4-((1E)-3-tert-butoxy-3-oxoprop-1-en-1-yl)benzoate;4-((E)-2-tert-butoxycarbonylvinyl)benzoic acid methyl ester;

Suppliers and Price of Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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Total 3 raw suppliers

Chemical Property of Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester

Chemical Property:

Melting Point:79.2 - 80.9 °C
PSA：52.60000
LogP:2.82810

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

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Hazard Codes:

MSDS Files:

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Technology Process of Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester

There total 5 articles about Benzoic acid, 4-[(1E)-3-(1,1-dimethylethoxy)-3-oxo-1-propenyl]-, methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1663-39-4,25232-27-3
tert-Butyl acrylate

: 619-44-3
methyl 4-iodobenzoate

: 683246-09-5
methyl (E)-4-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)benzoate

Guidance literature:: With C₃₆H₃₆Cl₂N₆Pd; triethylamine; In methanol; at 70 ℃; for 24h;
DOI:10.1016/j.jorganchem.2013.08.016

Reference yield: 98.0%

: 27784-76-5
tert-butyl diethylphosphonoacetate

: 1571-08-0
methyl 4-formylbenzoate

: 683246-09-5
methyl (E)-4-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)benzoate

Guidance literature:: tert-butyl diethylphosphonoacetate; With potassium tert-butylate; In tetrahydrofuran; at -5 ℃; for 1h;

methyl 4-formylbenzoate; In tetrahydrofuran; at -5 - 20 ℃;
DOI:10.1002/cmdc.202000754

Reference yield:

: 62327-21-3
tert-butyl dimethylphosphonoacetate

: 1571-08-0
methyl 4-formylbenzoate

: 683246-09-5
methyl (E)-4-(3-(tert-butoxy)-3-oxoprop-1-en-1-yl)benzoate

Guidance literature:: tert-butyl dimethylphosphonoacetate; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.5h;

methyl 4-formylbenzoate; In tetrahydrofuran; at 20 ℃; for 4h;