Technology Process of Silane,
[[3-(2-cyclohexen-1-ylmethyl)bicyclo[5.1.0]oct-2-en-1-yl]oxy]trimethyl-
There total 5 articles about Silane,
[[3-(2-cyclohexen-1-ylmethyl)bicyclo[5.1.0]oct-2-en-1-yl]oxy]trimethyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
(6-cyclohex-2-enylmethyl-cyclohepta-1,6-dienyloxy)-trimethyl-silane;
With
diethylzinc;
In
diethyl ether; hexane;
at 0 ℃;
diiodomethane;
In
diethyl ether; hexane;
at 20 ℃;
Further stages.;
DOI:10.1002/chem.200304827
- Guidance literature:
-
Multi-step reaction with 7 steps
1.1: 9-BBN / tetrahydrofuran / 48 h / 20 °C
1.2: 82 percent / NaOH; aq. H2O2 / tetrahydrofuran; ethanol / 1 h / Heating
2.1: 85 percent / oxalyl chloride; DMSO; Et3N / CH2Cl2 / 1 h / -78 - -10 °C
3.1: Li / diethyl ether / 1 h / -18 °C
3.2: diethyl ether / 2.5 h / -18 - 0 °C
4.1: aq. H3PO4 / diethyl ether; acetone
5.1: 1.25 g / aq. H3PO4 / pentane
6.1: LDA / tetrahydrofuran; hexane / 1 h / -78 °C
6.2: tetrahydrofuran; hexane / 2 h / -78 - 20 °C
7.1: Et2Zn / diethyl ether; hexane / 0 °C
7.2: 640 mg / diethyl ether; hexane / 20 °C
With
9-borabicyclo[3.3.1]nonane dimer; oxalyl dichloride; phosphoric acid; diethylzinc; lithium; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetone; pentane;
2.1: Swern oxidation;
DOI:10.1002/chem.200304827
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 85 percent / oxalyl chloride; DMSO; Et3N / CH2Cl2 / 1 h / -78 - -10 °C
2.1: Li / diethyl ether / 1 h / -18 °C
2.2: diethyl ether / 2.5 h / -18 - 0 °C
3.1: aq. H3PO4 / diethyl ether; acetone
4.1: 1.25 g / aq. H3PO4 / pentane
5.1: LDA / tetrahydrofuran; hexane / 1 h / -78 °C
5.2: tetrahydrofuran; hexane / 2 h / -78 - 20 °C
6.1: Et2Zn / diethyl ether; hexane / 0 °C
6.2: 640 mg / diethyl ether; hexane / 20 °C
With
oxalyl dichloride; phosphoric acid; diethylzinc; lithium; dimethyl sulfoxide; triethylamine; lithium diisopropyl amide;
In
tetrahydrofuran; diethyl ether; hexane; dichloromethane; acetone; pentane;
1.1: Swern oxidation;
DOI:10.1002/chem.200304827
