Diphenylisopropoxyborane

Base Information

Chemical Name:Diphenylisopropoxyborane
CAS No.:69737-51-5
Molecular Formula:C15H17BO
Molecular Weight:224.11
Hs Code.:
DSSTox Substance ID:DTXSID70499689
Wikidata:Q82350693

Synonyms:diphenylisopropoxyborane;69737-51-5;Propan-2-yl diphenylborinate;SCHEMBL7461066;DTXSID70499689;XVVNMEJXDISNRU-UHFFFAOYSA-N

Suppliers and Price of Diphenylisopropoxyborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Diphenylisopropoxyborane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:224.1372453
Heavy Atom Count:17
Complexity:187

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=CC=CC=C1)(C2=CC=CC=C2)OC(C)C

Technology Process of Diphenylisopropoxyborane

There total 8 articles about Diphenylisopropoxyborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 5419-55-6
Triisopropyl borate

: 591-51-5
phenyllithium

: 1692-26-8
bis(propan-2-yl) phenylboronate

: 69737-51-5
diphenylisopropoxyborane

Guidance literature:: With hydrogenchloride; tert.-butyl lithium; In diethyl ether; under N2; to cold (-98 °C) soln. of boron compd. in Et2O slowly added MeLi, stirred for 0.5 h, warmed to room temp., stirred for 0.5 h,Li(BMe4) detected by (11)B NMR, cooled to 0 °C, added soln. of HCl in Et2O, stirred for 15 min, warmed; not isolated, monitored by (11)B NMR;
DOI:10.1021/om50004a009

Reference yield: 90.0%

: 1692-26-8
bis(propan-2-yl) phenylboronate

: 591-51-5
phenyllithium

: 69737-51-5
diphenylisopropoxyborane

Guidance literature:: In diethyl ether; byproducts: LiCl, 2-propanol; 1 equiv of PhLi slowly adding to a soln. of the boronic ester at -78°C, stirring for 3 h at the same temp., 1 equiv of anhydrous HCl in ether adding, warming to room temp., stirring for 15 min; product content detd. by (11)B NMR spectrum;
DOI:10.1021/om00129a019

Reference yield: 87.0%

: 4406-77-3
2-Phenyl-1,3,2-dioxaborinane

: 591-51-5
phenyllithium

: 69737-51-5
diphenylisopropoxyborane

Guidance literature:: In diethyl ether; byproducts: LiCl, 2-propanol; 1 equiv of PhLi slowly adding to a soln. of the boronic ester at -78°C, stirring for 3 h at the same temp., 1 equiv of anhydrous HCl in ether adding, warming to room temp., decanting from the ppt. of LiCl, washing with ether, evavpg.; isolated by fractional distillation, identified by elem. anal., NMR, UVand mass spectra;
DOI:10.1021/om00129a019