1-Bromo-1,1,2,3,3,3-hexafluoropropane

Base Information

• Chemical Name: 1-Bromo-1,1,2,3,3,3-hexafluoropropane
• CAS No.: 2252-78-0
• Molecular Formula: C3H Br F6
• Molecular Weight: 230.935
• Hs Code.: 2903799090
• DSSTox Substance ID: DTXSID90862891
• Mol file: 2252-78-0.mol

Synonyms:1-Bromo-1,1,2,3,3,3-hexafluoropropane;2252-78-0;HCFC-226eaB1;SCHEMBL407691;DTXSID90862891;AKOS025117155;1-brom-1,1,2,3,3,3-hexafluorpropan;FT-0607424;A816243;1-bromanyl-1,1,2,3,3,3-hexakis(fluoranyl)propane

Chemical Property of 1-Bromo-1,1,2,3,3,3-hexafluoropropane

Chemical Property:

• Vapor Pressure: 497mmHg at 25°C
• Refractive Index: 1.303
• Boiling Point: 36.8°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.856g/cm³
• LogP: 2.87450
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 1
• Exact Mass: 229.91658
• Heavy Atom Count: 10
• Complexity: 117

Purity/Quality:

97% ^*data from raw suppliers

1-Bromo-1,1,2,3,3,3-hexafluoropropane 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(F)(F)F)(C(F)(F)Br)F

Technology Process of 1-Bromo-1,1,2,3,3,3-hexafluoropropane

There total 1 articles about 1-Bromo-1,1,2,3,3,3-hexafluoropropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

1,2-dibromohexafluoropropane (661-95-0) → 1-bromo-1,1,2,3,3,3-hexafluoro-propane (2252-78-0) + perfluoropropylene (116-15-4,13429-24-8,25120-07-4,6792-31-0) + 1,1,1,2,3,3-hexafluoropropane (431-63-0) + 2-bromo-1,1,1,2,3,3-hexafluoro-propane (2252-80-4)

Guidance literature:

With tri-n-butyl-tin hydride; for 1.5h; Product distribution; Heating;

DOI:10.1016/0022-1139(94)03153-Q

Reference yield:

1-bromo-1,1,2,3,3,3-hexafluoro-propane (2252-78-0) → perfluoropropyl bromide (422-85-5)

Guidance literature:

With cobalt (III) fluoride; at 200 ℃;

DOI:10.1039/jr9530003559

Reference yield:

1-bromo-1,1,2,3,3,3-hexafluoro-propane (2252-78-0) → 1,1,1,2,3,3,3-Heptafluoropropane (431-89-0) + freon-218 (76-19-7) + perfluoropropyl bromide (422-85-5)

Guidance literature:

at 200 ℃;

DOI:10.1039/jr9530003559

upstream raw materials:

1,2-dibromohexafluoropropane

Downstream raw materials:

perfluoropropyl bromide

1,1,1,2,3,3,3-Heptafluoropropane

freon-218