Benzene, 1-(3-bromo-1-methylpropyl)-4-methyl-, (R)-

Base Information

Chemical Name:Benzene, 1-(3-bromo-1-methylpropyl)-4-methyl-, (R)-
CAS No.:72843-32-4
Molecular Formula:C11H15Br
Molecular Weight:227.144
Hs Code.:

Synonyms:

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Chemical Property of Benzene, 1-(3-bromo-1-methylpropyl)-4-methyl-, (R)-

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Technology Process of Benzene, 1-(3-bromo-1-methylpropyl)-4-methyl-, (R)-

There total 10 articles about Benzene, 1-(3-bromo-1-methylpropyl)-4-methyl-, (R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 106035-79-4
(R)-3-(4-methylphenyl)-1-butanol

: 72843-32-4
1-((R)-3-Bromo-1-methyl-propyl)-4-methyl-benzene

Guidance literature:: With carbon tetrabromide; triphenylphosphine; In dichloromethane; at -40 ℃;
DOI:10.1039/a702667f

Reference yield:

: 4424-32-2
2-(4-methylphenyl)-1,3-propanediol

: 72843-32-4
1-((R)-3-Bromo-1-methyl-propyl)-4-methyl-benzene

Guidance literature:: Multi-step reaction with 8 steps

1: 84 percent / porcine pancreatic lipase / diethyl ether / Ambient temperature

2: Et₃N, DMAP / CH₂Cl₂ / Ambient temperature

3: NaBH₄ / dimethylsulfoxide / 60 °C

4: 88 percent / (i-Pr)2NEt / CH₂Cl₂ / Ambient temperature

5: 90 percent / 18-crown-6 / dimethylsulfoxide / 60 °C

6: 1.) DIBAL-H, 2.) 1 M aq. HCl / 1.) CH₂Cl₂, hexane, -78 deg C

7: NaBH₄ / methanol

8: 94 percent / Ph₃P, CBr₄ / CH₂Cl₂ / -40 °C

With hydrogenchloride; dmap; sodium tetrahydroborate; porcine pancreatic lipase; carbon tetrabromide; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 18-crown-6 ether; In methanol; diethyl ether; dichloromethane; dimethyl sulfoxide;
DOI:10.1039/a702667f

Reference yield:

: 131605-39-5
(R)-3-hydroxy-2-(4-methylphenyl)propyl acetate

: 72843-32-4
1-((R)-3-Bromo-1-methyl-propyl)-4-methyl-benzene

Guidance literature:: Multi-step reaction with 7 steps

1: Et₃N, DMAP / CH₂Cl₂ / Ambient temperature

2: NaBH₄ / dimethylsulfoxide / 60 °C

3: 88 percent / (i-Pr)2NEt / CH₂Cl₂ / Ambient temperature

4: 90 percent / 18-crown-6 / dimethylsulfoxide / 60 °C

5: 1.) DIBAL-H, 2.) 1 M aq. HCl / 1.) CH₂Cl₂, hexane, -78 deg C

6: NaBH₄ / methanol

7: 94 percent / Ph₃P, CBr₄ / CH₂Cl₂ / -40 °C

With hydrogenchloride; dmap; sodium tetrahydroborate; carbon tetrabromide; diisobutylaluminium hydride; triethylamine; N-ethyl-N,N-diisopropylamine; triphenylphosphine; 18-crown-6 ether; In methanol; dichloromethane; dimethyl sulfoxide;
DOI:10.1039/a702667f