Oxaziridine, 2-[(4-methylphenyl)sulfonyl]-3-(4-nitrophenyl)-, trans-

Base Information

• Chemical Name: Oxaziridine, 2-[(4-methylphenyl)sulfonyl]-3-(4-nitrophenyl)-, trans-
• CAS No.: 73844-95-8
• Molecular Formula: C₁₄H₁₂N₂O₅S
• Molecular Weight: 320.326
• Mol file: 73844-95-8.mol

Synonyms:

Chemical Property of Oxaziridine, 2-[(4-methylphenyl)sulfonyl]-3-(4-nitrophenyl)-, trans-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Oxaziridine, 2-[(4-methylphenyl)sulfonyl]-3-(4-nitrophenyl)-, trans-

There total 14 articles about Oxaziridine, 2-[(4-methylphenyl)sulfonyl]-3-(4-nitrophenyl)-, trans- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

N-tosyl-4-nitrobenzaldimine (13707-46-5) → 3-(4-nitrophenyl)-2-p-tolylsulfonyloxaziridine (73844-95-8,90687-53-9)

Guidance literature:

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; water;

Reference yield: 83.0%

N-tosyl-4-nitrobenzaldimine (13707-46-5) → (2S,3S)-3-(4-Nitro-phenyl)-2-(toluene-4-sulfonyl)-oxaziridine (73844-95-8,90687-53-9)

Guidance literature:

With dihydrogen peroxide; zinc(II) acetate dihydrate; sodium carbonate; carbonic acid dimethyl ester; In water; at 20 ℃; for 14h; Green chemistry;

DOI:10.1039/c6gc01394e

Reference yield:

(E)-4-methyl-N-(4-nitrobenzylidene)benzenesulfonamide (13707-46-5) → 3-(4-nitrophenyl)-2-p-tolylsulfonyloxaziridine (73844-95-8,90687-53-9)

Guidance literature:

With potassium hydroxide; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 0.0166667h;

DOI:10.1021/ol052250w

upstream raw materials:

N-tosyl-4-nitrobenzaldimine

p-nitrobenzaldehyde diethyl acetal

toluene-4-sulfonamide

4-nitrobenzaldehdye

Downstream raw materials:

N-tosyl-4-nitrobenzaldimine

Refernces

• 1、 Gu, Xin,Zhang, Yan,Xu, Zhen-Jiang,Che, Chi-Ming. "Iron(iii)-salan complexes catalysed highly enantioselective fluorination and hydroxylation of β-keto esters and N-Boc oxindoles". supporting information. p. 7870 - 7873. Retrieved 2014/07/08.
• 2、 Cudic, Mane,Herrmann, Rudolf. "Multinuclear Magnetic Resonance Study of Oxaziridines". . p. 461 - 467. Retrieved 2007/10/02.