2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:74213-49-3
Molecular Formula:C13H23BO2
Molecular Weight:222.135
Hs Code.:
European Community (EC) Number:817-617-3
Nikkaji Number:J1.932.361G

Synonyms:2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;74213-49-3;MFCD31390398;AKOS037621505;PS-19645;SY226117;E88450;EN300-658541;(Cyclohexylidenemethyl)boronic Acid Pinacol Ester;Z2327672358

Suppliers and Price of 2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:1
Exact Mass:222.1791101
Heavy Atom Count:16
Complexity:270

Purity/Quality:: 97% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C=C2CCCCC2

Technology Process of 2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 13 articles about 2-(Cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 72824-04-5,83947-58-4,83947-59-5,72824-05-6
4,4,5,5-tetramethyl-2-(1-propenyl)-1,3,2-dioxaborolane

: 1192-37-6
methylenecyclohexane

: 74213-49-3
2-(cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In dichloromethane; for 12h; Heating;
DOI:10.1021/jo0345345

Reference yield: 87.0%

: 83947-62-0
pinacol lithio(trimethylsilyl)methaneboronate

: 108-94-1,11119-77-0,9003-41-2,9075-99-4
cyclohexanone

: 74213-49-3
2-(cyclohexylidenemethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:: In tetrahydrofuran; byproducts: bis(trimethylsilyl) ether; ketone was added by syringe at -78°C under Ar to a THF soln. of the carbanion, the mixt. was stirred 2-3 h at -78°C and allowed to warm to 25°C overnight; reaction mixt. was treated with cold 2 M HCl, extd. with 5:1 Et2O-CH2Cl2, ext. washed with satd. NaCl, dried over MgSO4 and distilled; elem. anal.;
DOI:10.1021/om00074a005