Ethenesulfonic acid, 2-propenyl ester

Base Information

• Chemical Name: Ethenesulfonic acid, 2-propenyl ester
• CAS No.: 7459-72-5
• Molecular Formula: C5H8O3S
• Molecular Weight: 148.183
• Mol file: 7459-72-5.mol

Synonyms:allylvinylsulfonate;allyl vinylsulfonate;

Chemical Property of Ethenesulfonic acid, 2-propenyl ester

Chemical Property:

• Boiling Point: 226.0±23.0 °C(Predicted)
• PSA: 51.75000
• Density: 1.151±0.06 g/cm3(Predicted)
• LogP: 1.74310

Purity/Quality:

99%, ^*data from raw suppliers

Allylethenesulfonate 90% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Ethenesulfonic acid, 2-propenyl ester

There total 2 articles about Ethenesulfonic acid, 2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

vinylsulfonyl chloride (6608-47-5) + allyl alcohol (107-18-6) → allyl ethenesulfonate (7459-72-5)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 ℃; for 0.75h;

DOI:10.1055/s-2004-822408

Reference yield: 47.0%

2-Chloroethanesulfonyl chloride (1622-32-8) + allyl alcohol (107-18-6) → allyl ethenesulfonate (7459-72-5)

Guidance literature:

With triethylamine; In tetrahydrofuran; at -40 - -20 ℃; for 5h;

Reference yield: 100.0%

allyl ethenesulfonate (7459-72-5) → 1-propenyl-1,3-sulfonic acid lactone (21806-61-1)

Guidance literature:

tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; In benzene; at 70 ℃; for 2h;

upstream raw materials:

vinylsulfonyl chloride

allyl alcohol

2-Chloroethanesulfonyl chloride

Downstream raw materials:

1-propenyl-1,3-sulfonic acid lactone

triallyl phosphate

Refernces

• 1、 Le Flohic, Alexandre,Meyer, Christophe,Cossy, Janine. "Reactivity of unsaturated sultones synthesized from unsaturated alcohols by ring-closing metathesis. Application to the racemic synthesis of the originally proposed structure of mycothiazole". . p. 9017 - 9037. Retrieved 2007/10/03.
• 2、 Karsch, Sandra,Freitag, Dirk,Schwab, Pia,Metz, Peter. "Ring closing metathesis in the synthesis of sultones and sultams". . p. 1696 - 1712. Retrieved 2007/10/03.