Diethyl 2-(furan-2-ylmethylene)succinate

Base Information

Chemical Name:Diethyl 2-(furan-2-ylmethylene)succinate
CAS No.:74531-23-0
Molecular Formula:C₁₃H₁₆O₅
Molecular Weight:252.267
Hs Code.:
NSC Number:61736
DSSTox Substance ID:DTXSID70422210
Wikidata:Q82234068

Synonyms:NSC61736;74531-23-0;DTXSID70422210;NSC-61736;Diethyl 2-(furan-2-ylmethylene)succinate

Suppliers and Price of Diethyl 2-(furan-2-ylmethylene)succinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of Diethyl 2-(furan-2-ylmethylene)succinate

Chemical Property:

Vapor Pressure:2.83E-05mmHg at 25°C
Boiling Point:356.9°Cat760mmHg
Flash Point:169.7°C
Density:1.151g/cm³
XLogP3:1.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:252.09977361
Heavy Atom Count:18
Complexity:321

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)CC(=CC1=CC=CO1)C(=O)OCC
Isomeric SMILES:CCOC(=O)C/C(=C/C1=CC=CO1)/C(=O)OCC

Technology Process of Diethyl 2-(furan-2-ylmethylene)succinate

There total 4 articles about Diethyl 2-(furan-2-ylmethylene)succinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 98-01-1
furfural

: 623-91-6
diethyl Fumarate

: 74531-23-0
ethyl (E)-4-(2-furyl)-3-ethoxycarbonylbut-3-enoate

Guidance literature:: With 1,2,2,3,4,4-hexamethylphosphetane 1-oxide; In acetic acid butyl ester; at 120 ℃; for 24h; stereoselective reaction; Inert atmosphere; Schlenk technique;
DOI:10.1039/d1gc00953b

Reference yield: 84.0%

: 98-01-1
furfural

: 7071-15-0
diethyl 2-(diethoxyphosphoryl)succinate

: 74531-23-0
ethyl (E)-4-(2-furyl)-3-ethoxycarbonylbut-3-enoate

Guidance literature:: With sodium ethanolate; In ethanol; at 0 ℃; for 2h;

Reference yield:

: 141-05-9
Diethyl maleate

: 74531-23-0
ethyl (E)-4-(2-furyl)-3-ethoxycarbonylbut-3-enoate

Guidance literature:: Multi-step reaction with 2 steps

1: 1) Na / 1) 50 deg C; 2) 50 deg C, 0.5 h

2: 84 percent / NaOC₂H₅ / ethanol / 2 h / 0 °C

With sodium ethanolate; sodium; In ethanol;