Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester

Base Information

• Chemical Name: Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester
• CAS No.: 75002-85-6
• Molecular Formula: C8H12O3
• DSSTox Substance ID: DTXSID80470585
• Nikkaji Number: J2.261.411H

Synonyms:75002-85-6;Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester;SCHEMBL11158507;DTXSID80470585

Chemical Property of Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester

Chemical Property:

• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 156.078644241
• Heavy Atom Count: 11
• Complexity: 176

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C1C(C1C=O)C

Technology Process of Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester

There total 5 articles about Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

diazoacetic acid ethyl ester (623-73-4) + trans-Crotonaldehyde (123-73-9,4170-30-3) → ethyl 2-formyl-3-methyl-cyclopropane-1-carboxylate (75002-85-6,318990-36-2)

Guidance literature:

With tetrafluoroboric acid diethyl ether; In dichloromethane; at -78 ℃; for 26h;

DOI:10.1016/j.tetlet.2005.10.148

Reference yield:

trans-Crotonaldehyde (123-73-9,4170-30-3) + tetrahydrothiophene ylid → ethyl 2-formyl-3-methyl-cyclopropane-1-carboxylate (75002-85-6,318990-36-2)

Guidance literature:

In acetone;

Reference yield:

ethyl (dimethylsulfuranylidene)acetate (7380-81-6) + (E)-but-2-enol (504-61-0,542-72-3) → ethyl 2-formyl-3-methyl-cyclopropane-1-carboxylate (75002-85-6,318990-36-2)

Guidance literature:

With manganese(IV) oxide; In dichloromethane; for 6h; Molecular sieve; Reflux;

DOI:10.1021/acs.orglett.1c03607

upstream raw materials:

ethyl (dimethylsulfuranylidene)acetate

crotonaldehyde

trans-Crotonaldehyde

diazoacetic acid ethyl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 75002-85-6 Cyclopropanecarboxylic acid, 2-formyl-3-methyl-, ethyl ester

Send

Send

Metric Ton KG G Pound L ML

Send

Send