Benzene, 1,3-butadienyl-, (Z)-

Base Information

• Chemical Name: Benzene, 1,3-butadienyl-, (Z)-
• CAS No.: 31915-94-3
• Molecular Formula: C10H10
• Molecular Weight: 130.189
• Nikkaji Number: J192.732I
• Mol file: 31915-94-3.mol

Synonyms:(Z)-Buta-1,3-dien-1-ylbenzene;1-Phenyl-1,3-butadiene, (Z)-;31915-94-3;cis-Phenyl-butadien;Benzene, 1,3-butadienyl-, (Z)-;(Z)-beta-Vinylstyrene;1-Phenyl-1,3-butadiene(Z);[(1Z)-buta-1,3-dienyl]-benzene

Chemical Property of Benzene, 1,3-butadienyl-, (Z)-

Chemical Property:

• Vapor Pressure: 0.355mmHg at 25°C
• Melting Point: -57°C
• Refractive Index: 1.6095
• Boiling Point: 205.6°Cat760mmHg
• Flash Point: 70.8°C
• PSA: 0.00000
• Density: 0.916g/cm³
• LogP: 2.88580
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 130.078250319
• Heavy Atom Count: 10
• Complexity: 116

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CC=CC1=CC=CC=C1
• Isomeric SMILES: C=C/C=C\C1=CC=CC=C1

Technology Process of Benzene, 1,3-butadienyl-, (Z)-

There total 60 articles about Benzene, 1,3-butadienyl-, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

threo-1-phenyl-2-(trimethylsilyl)-3-buten-1-ol (85125-31-1) → (Z)-1-Phenylbuta-1,3-diene (31915-94-3)

Guidance literature:

With potassium hydride; In tetrahydrofuran; for 0.166667h;

DOI:10.1016/S0040-4039(00)85661-0

Reference yield: 84.0%

(1S,2R)-1-Phenyl-2-trimethylsilanyl-but-3-en-1-ol (68724-63-0,79309-70-9,85125-28-6,85125-31-1,139402-80-5,140631-00-1) → (Z)-1-Phenylbuta-1,3-diene (31915-94-3)

Guidance literature:

With potassium hydride; In tetrahydrofuran; for 0.166667h;

DOI:10.1016/S0040-4039(01)90542-8

Reference yield: 79.0%

(Z)-styryl iodide (57918-63-5) + Methyltriphenylphosphonium bromide (1779-49-3) + N,N-dimethyl-formamide (68-12-2,33513-42-7) → (Z)-1-Phenylbuta-1,3-diene (31915-94-3)

Guidance literature:

With potassium tert-butylate; tert.-butyl lithium; In tetrahydrofuran; pentane; at -75 - 25 ℃; for 4h;

DOI:10.1002/(SICI)1099-0690(199912)1999:12<3263::AID-EJOC3263>3.0.CO;2-U

upstream raw materials:

(4ar,8at)-4a,8a-dihydro-naphthalene

allylbenzene

bromomethanesulfonyl bromide

(E)-buta-1,3-dienylbenzene

Downstream raw materials:

1,1-Dimethoxy-2-(trans-styryl)cyclopropan

3-Phenyl-4-cyclohexen-1,1,2,2-tetracarbonitril

1-[4-((1E,3E)-4-Phenyl-buta-1,3-dienyl)-phenyl]-ethanone

(2R,3S)-2-Phenyl-3-vinyl-cyclopropanecarboxylic acid ethyl ester