Sodium pyridin-3-olate

Base Information

• Chemical Name: Sodium pyridin-3-olate
• CAS No.: 52536-09-1
• Molecular Formula: C5H5 N O . Na
• Molecular Weight: 117.083
• Hs Code.: 29333999
• European Community (EC) Number: 257-995-1
• DSSTox Substance ID: DTXSID40200527
• Nikkaji Number: J295.690J
• Mol file: 52536-09-1.mol

Synonyms:Sodium pyridin-3-olate;52536-09-1;3-Hydroxypyridine sodium salt;sodium;pyridin-3-olate;EINECS 257-995-1;Sodiumpyridin-3-olate;Sodium pyridine-3-olate;C5H5NO.Na;C5-H5-N-O.Na;3-Hydroxypyridine sodium salt?;DTXSID40200527;AKOS006230241;FT-0654800;A829130;J-512658

Chemical Property of Sodium pyridin-3-olate

Chemical Property:

• Melting Point: 300 ºC
• Boiling Point: 318.9 °C at 760 mmHg
• Flash Point: 146.6 °C
• PSA: 35.95000
• Density: g/cm³
• LogP: 1.22540
• Storage Temp.: Sealed in dry,Room Temperature
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 117.01905803
• Heavy Atom Count: 8
• Complexity: 60.4

Purity/Quality:

98% ^*data from raw suppliers

Sodium pyridin-3-olate 95+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CN=C1)[O-].[Na+]

Technology Process of Sodium pyridin-3-olate

There total 1 articles about Sodium pyridin-3-olate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-HYDROXYPYRIDINE (109-00-2) → 3-pyridylphenolate sodium salt (52536-09-1)

Guidance literature:

With sodium hydride; In 1,2-dimethoxyethane; at 0 ℃; for 0.333333h;

Reference yield: 60.0%

2-Chloro-3-nitropyridine (5470-18-8,34515-82-7) + 3-pyridylphenolate sodium salt (52536-09-1) → 2-(3'-pyridyloxy)-3-nitropyridine (76594-24-6)

Guidance literature:

In ethanol; Ambient temperature; overnight;

DOI:10.1002/jhet.5570170601

Reference yield: 28.0%

C12H7FN2O (1364440-74-3) + 3-pyridylphenolate sodium salt (52536-09-1) → 2,4-bis-(3-pyridyloxy)benzonitrile (1364440-81-2)

Guidance literature:

In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 0.25h; Microwave irradiation;

DOI:10.1016/j.bmcl.2012.01.076

upstream raw materials:

3-HYDROXYPYRIDINE

Downstream raw materials:

2-(3'-pyridyloxy)-3-nitropyridine

2-(Pyridin-3-yloxy)-benzonitrile

2,4-bis-(3-pyridyloxy)benzonitrile

C₁₂H₇FN₂O