Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate

Base Information

Chemical Name:Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate
CAS No.:79663-63-1
Molecular Formula:C9H14O3
Molecular Weight:170.208
Hs Code.:
DSSTox Substance ID:DTXSID601261902

Synonyms:Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate;DTXSID601261902;79663-63-1

Suppliers and Price of Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate

Chemical Property:

XLogP3:0.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:170.094294304
Heavy Atom Count:12
Complexity:196

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCOC(=O)C1=CC(CCC1)O

Technology Process of Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate

There total 3 articles about Ethyl 3-hydroxy-1-cyclohexene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 25017-79-2
ethyl 3-oxocyclohex-1-ene-1-carboxylate

: 79663-63-1
ethyl 3-hydroxycyclohex-1-enecarboxylate

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride heptahydrate; In methanol; at 0 ℃;
DOI:10.1039/c7gc02215h

Reference yield:

: 18448-47-0
methyl cyclohex-1-ene-1-carboxylate

: 79663-63-1
ethyl 3-hydroxycyclohex-1-enecarboxylate

Guidance literature:: Multi-step reaction with 3 steps

1: sulfuric acid

2: chromium(VI) oxide; acetic anhydride / acetic acid; dichloromethane / 0 - 5 °C

3: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0 °C

With chromium(VI) oxide; sodium tetrahydroborate; cerium(III) chloride heptahydrate; sulfuric acid; acetic anhydride; In methanol; dichloromethane; acetic acid;
DOI:10.1039/c7gc02215h

Reference yield:

: 1617-22-7
cyclohex-1-enecarboxylic acid ethyl ester

: 79663-63-1
ethyl 3-hydroxycyclohex-1-enecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: chromium(VI) oxide; acetic anhydride / acetic acid; dichloromethane / 0 - 5 °C

2: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0 °C

With chromium(VI) oxide; sodium tetrahydroborate; cerium(III) chloride heptahydrate; acetic anhydride; In methanol; dichloromethane; acetic acid;
DOI:10.1039/c7gc02215h