Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-

Base Information

Chemical Name:Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-
CAS No.:809233-47-4
Molecular Formula:C19H32S2Si
Molecular Weight:352.681
Hs Code.:
DSSTox Substance ID:DTXSID80479290

Synonyms:809233-47-4;Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-;DTXSID80479290

Suppliers and Price of Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 1 raw suppliers

Chemical Property of Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:5
Exact Mass:352.17146990
Heavy Atom Count:22
Complexity:318

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)[Si](C(C)C)(C(C)C)C1(SCCCS1)C2=CC=CC=C2

Technology Process of Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)-

There total 3 articles about Silane, tris(1-methylethyl)(2-phenyl-1,3-dithian-2-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 5425-44-5
2-Phenyl-[1,3]dithiane

: 13154-24-0
triisopropylsilyl chloride

: 809233-47-4
triisopropyl-(2-phenyl-[1,3]dithian-2-yl)-silane

Guidance literature:: 2-Phenyl-[1,3]dithiane; With n-butyllithium; In tetrahydrofuran; pentane; at 0 ℃;

triisopropylsilyl chloride; In tetrahydrofuran; pentane;
DOI:10.1016/j.tet.2004.10.099

Reference yield: 70.0%

: 5425-44-5
2-Phenyl-[1,3]dithiane

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 809233-47-4
triisopropyl-(2-phenyl-[1,3]dithian-2-yl)-silane

Guidance literature:: 2-Phenyl-[1,3]dithiane; With n-butyllithium; In tetrahydrofuran; hexane; at 0 ℃; for 0.166667h;

triisopropylsilyl trifluoromethanesulfonate; In tetrahydrofuran; hexane; at 0 - 20 ℃;
DOI:10.1039/b405786d

Reference yield:

: 100-52-7
benzaldehyde

: 809233-47-4
triisopropyl-(2-phenyl-[1,3]dithian-2-yl)-silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: boron trifluoride diethyl etherate / dichloromethane / 3 h / 0 - 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

2.2: 1 h / -78 - 20 °C / Inert atmosphere

With n-butyllithium; boron trifluoride diethyl etherate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jacs.7b05165