2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]-

Base Information

Chemical Name:2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]-
CAS No.:817203-17-1
Molecular Formula:C14H22OSi
Molecular Weight:234.40900
Hs Code.:

Synonyms:2-Cyclohexen-1-one,2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl];2,4,4-trimethyl-3-(trimethylsilylethynyl)cyclohex-2-en-1-one;VOJUUXJKVQGETL-UHFFFAOYSA;InChI=1/C14H22OSi/c1-11-12(8-10-16(4,5)6)14(2,3)9-7-13(11)15/h7,9H2,1-6H3;

Suppliers and Price of 2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]-

Chemical Property:

PSA：17.07000
LogP:3.57280

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of 2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]-

There total 3 articles about 2-Cyclohexen-1-one, 2,4,4-trimethyl-3-[(trimethylsilyl)ethynyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

: 817203-16-0
rac-2,6,6-trimethyl-1-(trimethylsilylethynyl)cyclohex-2-en-1-ol

: 817203-17-1
2,4,4-trimethyl-3-(trimethylsilylethynyl)cyclohex-2-en-1-one

Guidance literature:: With silica gel; pyridinium chlorochromate; In dichloromethane; at 25 ℃; for 4h;
DOI:10.1039/b411585f

Reference yield:

: 20013-73-4
2,6,6-trimethylcyclohex-2-en-1-one

: 817203-17-1
2,4,4-trimethyl-3-(trimethylsilylethynyl)cyclohex-2-en-1-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C

1.2: 70 percent / tetrahydrofuran; hexane / -78 - 0 °C

2.1: 67 percent / PCC; silica gel / CH₂Cl₂ / 4 h / 25 °C

With n-butyllithium; silica gel; pyridinium chlorochromate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/b411585f

Reference yield:

: 1066-54-2
trimethylsilylacetylene

: 817203-17-1
2,4,4-trimethyl-3-(trimethylsilylethynyl)cyclohex-2-en-1-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / 0 °C

1.2: 70 percent / tetrahydrofuran; hexane / -78 - 0 °C

2.1: 67 percent / PCC; silica gel / CH₂Cl₂ / 4 h / 25 °C

With n-butyllithium; silica gel; pyridinium chlorochromate; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1039/b411585f