Methanone, [2-(acetyloxy)bicyclo[2.2.1]hept-1-yl]phenyl-, exo-

Base Information

Chemical Name:Methanone, [2-(acetyloxy)bicyclo[2.2.1]hept-1-yl]phenyl-, exo-
CAS No.:82027-31-4
Molecular Formula:C16H18O3
Molecular Weight:258.317
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Methanone, [2-(acetyloxy)bicyclo[2.2.1]hept-1-yl]phenyl-, exo-

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:: SDS file from LookChem

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Technology Process of Methanone, [2-(acetyloxy)bicyclo[2.2.1]hept-1-yl]phenyl-, exo-

There total 12 articles about Methanone, [2-(acetyloxy)bicyclo[2.2.1]hept-1-yl]phenyl-, exo- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82027-11-0
Methanesulfonic acid (1R,2S,4S)-2-benzoyl-bicyclo[2.2.1]hept-2-yl ester

: 82027-30-3
Acetic acid (1S,2R,4R,6S)-6-benzoyl-bicyclo[2.2.1]hept-2-yl ester

: 80325-62-8
1-benzoyltricyclo<2.2.1>heptane

: 82027-31-4
Acetic acid (1S,2R,4S)-1-benzoyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: With sodium acetate; In acetic acid; at 100 ℃; for 10h; Yield given. Yields of byproduct given;
DOI:10.1021/ja00379a018

Reference yield:

: 82027-17-6
Phenyl-(2-trimethylsilanyloxy-bicyclo[2.2.1]hept-2-yl)-methanone

: 82027-31-4
Acetic acid (1S,2R,4S)-1-benzoyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) H₂, 2.) 0.001M trifluoroacetic acid in MeOH / 1.) Pd/C / 1.) ether, RT, 55 psi, 75 min, 2.) MeOH, RT, 20 h

2: 100 percent / triethylamine, m-chloroperbenzoic acid / CH₂Cl₂ / -40 - 25 °C

3: 0.05M sodium acetate, acetic acid / 1.5 h / 100 °C / Heating

With hydrogen; sodium acetate; acetic acid; triethylamine; 3-chloro-benzenecarboperoxoic acid; trifluoroacetic acid; palladium on activated charcoal; In dichloromethane;
DOI:10.1021/jo00211a029

Reference yield:

: 497-38-1
Norbornan-2-on

: 82027-31-4
Acetic acid (1S,2R,4S)-1-benzoyl-bicyclo[2.2.1]hept-2-yl ester

Guidance literature:: Multi-step reaction with 5 steps

1: LDA / hexane; tetrahydrofuran / 1.) -60 deg C, 5 min, 2.) -100 deg C, 3.) warm to room temperature

2: 5.1 g / 0.3 M NaOCH₃ / methanol / 2.5 h

3: Et₃N / -78 - 0 °C

4: 85percent m-chloroperbenzoic acid / CH₂Cl₂ / 1.5 h

5: CH₃COONa / acetic acid / 10 h / 100 °C

With sodium methylate; sodium acetate; triethylamine; 3-chloro-benzenecarboperoxoic acid; lithium diisopropyl amide; In tetrahydrofuran; methanol; hexane; dichloromethane; acetic acid;
DOI:10.1021/ja00379a018