Synonyms:2-norbornanone;norcamphor;norcamphor, (+-)-isomer
99% *data from raw suppliers
2-Norbornanone *data from reagent suppliers
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There total 184 articles about Norcamphor which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
Reference yield: 99.0%
Reference yield: 94.0%
Reference yield: 85.0%
The research investigates the deoxygenation of aldehydes and ketones using phenyl(tribromomethyl)mercury, which generates dibromocarbene. This study demonstrates that the formation of carbon monoxide from the reaction of dibromocarbene with various aldehydes and ketones is a general reaction, contrary to earlier suggestions that mercurial carbene precursors might not react with simple aliphatic ketones. The key chemicals involved in this research include phenyl(tribromomethyl)mercury as the source of dibromocarbene, a variety of aldehydes such as benzaldehyde and propionaldehyde, and ketones like acetone, cyclohexanone, and norcamphor. The reaction typically involves treating these carbonyl compounds with phenyl(tribromomethyl)mercury in benzene at 75-80°C for 4 hours, resulting in the production of carbon monoxide with yields ranging from about 16% to 46%. The study also explores the mechanistic aspects of the reaction, suggesting that the formation of carbon monoxide involves the rearrangement of an initially formed carbonyl ylide to alkoxyhalocarbene, followed by the formation of dihalide and CO.
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