2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde

Base Information

• Chemical Name: 2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde
• CAS No.: 83476-95-3
• Molecular Formula: C12H14OS
• Molecular Weight: 206.309
• DSSTox Substance ID: DTXSID90510108
• Mol file: 83476-95-3.mol

Synonyms:83476-95-3;2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde;SCHEMBL4439793;DTXSID90510108;2-(3-methylbut-2-enylthio)benzaldehyde

Chemical Property of 2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde

Chemical Property:

• XLogP3: 3.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 206.07653624
• Heavy Atom Count: 14
• Complexity: 206

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=CCSC1=CC=CC=C1C=O)C

Technology Process of 2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde

There total 1 articles about 2-[(3-Methylbut-2-en-1-yl)sulfanyl]benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-formylthiophenol (29199-11-9) + prenyl bromide (870-63-3) → 2-[(3-methylbut-2-enyl)sulfanyl]benzaldehyde (83476-95-3)

Guidance literature:

2-formylthiophenol; With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 0.25h;

prenyl bromide; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1039/c9cc01521c

Reference yield: 88.0%

2-[(3-methylbut-2-enyl)sulfanyl]benzaldehyde (83476-95-3) + trimethylsilylacetylene (1066-54-2) → C14H14OS

Guidance literature:

trimethylsilylacetylene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

2-[(3-methylbut-2-enyl)sulfanyl]benzaldehyde; In tetrahydrofuran; diethyl ether; at -78 ℃; for 0.5h; Inert atmosphere; Schlenk technique;

DOI:10.1002/asia.201301264

Reference yield: 78.0%

1-acetyl-2,3-dihydro-1H-indol-3-one (16800-68-3) + 2-[(3-methylbut-2-enyl)sulfanyl]benzaldehyde (83476-95-3) → 1-acetyl-2,3-dihydro-2-{2-[(3-methylbut-2-enyl)sulfanyl]benzylidene}-1H-indol-3-one

Guidance literature:

With piperidine; In toluene; at 110 ℃; for 4h;

DOI:10.1002/hlca.200390218

upstream raw materials:

2-formylthiophenol

prenyl bromide

Downstream raw materials:

C₁₄H₁₆OS