(e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester

Base Information

Chemical Name:(e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester
CAS No.:67249-05-2
Molecular Formula:C16H13 Cl O2
Molecular Weight:272.731
Hs Code.:
NSC Number:89114

Synonyms:NSC89114;67249-05-2;(e)-4-[2-(4-chloro-phenyl)-vinyl]-benzoic acid methyl ester;NSC-89114

Suppliers and Price of (e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of (e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester

Chemical Property:

Vapor Pressure:8.66E-07mmHg at 25°C
Boiling Point:405.6°Cat760mmHg
Flash Point:212.4°C
Density:1.225g/cm³
XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:272.0604073
Heavy Atom Count:19
Complexity:311

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=CC=C(C=C1)C=CC2=CC=C(C=C2)Cl
Isomeric SMILES:COC(=O)C1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)Cl

Technology Process of (e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester

There total 17 articles about (e)-4-[2-(4-Chloro-phenyl)-vinyl]-benzoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 619-44-3
methyl 4-iodobenzoate

: 67249-05-2
(E)-methyl 4-(4-chlorostyryl)benzoate

Guidance literature:: With triethylamine; In water; N,N-dimethyl-formamide; at 90 ℃; for 21h;
DOI:10.1016/j.molcata.2014.02.025

Reference yield: 77.0%

: 619-44-3
methyl 4-iodobenzoate

: 66482-29-9,125428-11-7,66482-30-2
1-[(E)-2-bromoethenyl]-4-chlorobenzene

: 67249-05-2
(E)-methyl 4-(4-chlorostyryl)benzoate

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 4,4'-di-tert-butyl-2,2'-bipyridine; lithium chloride; magnesium chloride; zinc; In tetrahydrofuran; at 0 - 20 ℃; for 15h; chemoselective reaction; Schlenk technique; Sealed tube; Inert atmosphere;
DOI:10.1002/anie.201607959