Oxacyclohexadec-12-en-2-one, (12Z)-

Base Information

Chemical Name:Oxacyclohexadec-12-en-2-one, (12Z)-
CAS No.:111879-79-9
Molecular Formula:C15H26 O2
Molecular Weight:238.37
Hs Code.:
UNII:88LWK3MR1Y
DSSTox Substance ID:DTXSID50888850
Wikidata:Q82868600
Mol file:111879-79-9.mol

Synonyms:Oxacyclohexadec-12-en-2-one, (12Z)-;88LWK3MR1Y;Oxacyclohexadecen-2-one, (12Z)-;111879-79-9;UNII-88LWK3MR1Y;SCHEMBL291215;DTXSID50888850;OXACYCLOHEXADECENONE, (12Z)-;OXACYCLOHEXADEC-13-EN-2-ONE, (12Z)-

Suppliers and Price of Oxacyclohexadec-12-en-2-one, (12Z)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Oxacyclohexadec-12-en-2-one, (12Z)-

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:383.719°C at 760 mmHg
Flash Point:161.241°C
Density:0.901g/cm³
XLogP3:5.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:238.193280068
Heavy Atom Count:17
Complexity:221

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCCCC=CCCCOC(=O)CCCC1
Isomeric SMILES:C1CCCC/C=C\CCCOC(=O)CCCC1

Technology Process of Oxacyclohexadec-12-en-2-one, (12Z)-

There total 10 articles about Oxacyclohexadec-12-en-2-one, (12Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 174390-08-0,32539-80-3
1-hydroperoxy-16-oxabicyclo[10.4.0]hexadecane

: 111879-81-3
trans-pentadec-12-en-15-olide

: 111879-81-3
trans-pentadec-12-en-15-olide

: 111879-80-2,423773-57-3
habanolide

: 111879-79-9,423773-57-3
(6Z)-2-oxa-6-cyclohexadecen-1-one

Guidance literature:: With copper(II) stearate; In toluene; at 100 ℃; for 1.33333h;

Reference yield:

: 3003-84-7
Tetrahydrofurfuryl chloride

: 111879-79-9,423773-57-3
(6Z)-2-oxa-6-cyclohexadecen-1-one

Guidance literature:: Multi-step reaction with 8 steps

1.1: LiNH₂; NH₃ liquid / 1 h / 20 °C

1.2: 77 percent / HMPA / tetrahydrofuran / 6 h / 20 °C

2.1: quinoline; MeOH / Lindlar catalyst / 5 h / 20 °C

3.1: pyridine; DMAP / CH₂Cl₂ / 2 h / 20 °C

4.1: aq. HCl / 2 h / 20 °C

5.1: 82 percent / PCC / CH₂Cl₂ / 3 h / 20 °C

6.1: 76 percent / alkaline Ag₂O / ethanol / 8 h / 20 °C

7.1: Boc₂O; Et₃N / 20 °C

8.1: DMAP / toluene / 90 - 95 °C

With pyridine; quinoline; hydrogenchloride; methanol; dmap; lithium amide; di-tert-butyl dicarbonate; alkaline Ag₂O; ammonia; triethylamine; pyridinium chlorochromate; Lindlar's catalyst; In ethanol; dichloromethane; toluene; 1.1: Ring cleavage / 1.2: Substitution / 2.1: Catalytic hydrogenation / 3.1: Acetylation / 4.1: Hydrolysis / 5.1: Oxidation / 6.1: Oxidation / 7.1: Acylation / 8.1: Cyclization;
DOI:10.1016/S0040-4020(99)00718-8

Reference yield:

: 51795-88-1
1-bromo-10-(tetrahydropyranyloxy)decane

: 111879-79-9,423773-57-3
(6Z)-2-oxa-6-cyclohexadecen-1-one

Guidance literature:: Multi-step reaction with 8 steps

1.1: LiNH₂; NH₃ liquid / 1 h / 20 °C

1.2: 77 percent / HMPA / tetrahydrofuran / 6 h / 20 °C

2.1: quinoline; MeOH / Lindlar catalyst / 5 h / 20 °C

3.1: pyridine; DMAP / CH₂Cl₂ / 2 h / 20 °C

4.1: aq. HCl / 2 h / 20 °C

5.1: 82 percent / PCC / CH₂Cl₂ / 3 h / 20 °C

6.1: 76 percent / alkaline Ag₂O / ethanol / 8 h / 20 °C

7.1: Boc₂O; Et₃N / 20 °C

8.1: DMAP / toluene / 90 - 95 °C

With pyridine; quinoline; hydrogenchloride; methanol; dmap; lithium amide; di-tert-butyl dicarbonate; alkaline Ag₂O; ammonia; triethylamine; pyridinium chlorochromate; Lindlar's catalyst; In ethanol; dichloromethane; toluene; 1.1: Ring cleavage / 1.2: Substitution / 2.1: Catalytic hydrogenation / 3.1: Acetylation / 4.1: Hydrolysis / 5.1: Oxidation / 6.1: Oxidation / 7.1: Acylation / 8.1: Cyclization;
DOI:10.1016/S0040-4020(99)00718-8