Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane

Base Information

Chemical Name:Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane
CAS No.:84666-31-9
Molecular Formula:C₂₂H₃₈OSn
Molecular Weight:437.253
Hs Code.:
DSSTox Substance ID:DTXSID001211266

Synonyms:DTXSID001211266;Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane;84666-31-9

Suppliers and Price of Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:14
Exact Mass:438.194468
Heavy Atom Count:24
Complexity:285

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C=CCOCC1=CC=CC=C1
Isomeric SMILES:CCCC[Sn](CCCC)(CCCC)/C=C/COCC1=CC=CC=C1

Technology Process of Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane

There total 6 articles about Tributyl[(1E)-3-(phenylmethoxy)-1-propen-1-yl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 82994-41-0,81925-29-3,74141-12-1,74141-13-2
(E)-3-(tri-n-butylstannyl)-2-propen-1-ol

: 100-39-0
benzyl bromide

: 84666-31-9,109669-46-7,243662-95-5
<(1E)-3-(benzyloxy)-1-propen-1-yl>tributylstannate

Guidance literature:: (E)-3-(tri-n-butylstannyl)-2-propen-1-ol; With potassium hexamethylsilazane; In tetrahydrofuran; at -78 ℃; for 0.166667h; Inert atmosphere;

benzyl bromide; With triethylamine; In tetrahydrofuran; at -78 - 0 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jacs.8b12647

Reference yield: 62.0%

: 4039-82-1
Benzyl propargyl ether

: 688-73-3
tri-n-butyl-tin hydride

: 84666-32-0
C₆H₅CH₂CH₂C(Sn(C₄H₉)3)CH₂O

: 84666-31-9,109669-46-7,243662-95-5
<(1E)-3-(benzyloxy)-1-propen-1-yl>tributylstannate

Guidance literature:: tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; hydrostannylation, at room temperature, mixture was stood for 10 minutes; removal of solvent (vacuo), flash chromy. (silica gel, dichloromethane);

Reference yield:

: 4039-82-1
Benzyl propargyl ether

: 688-73-3
tri-n-butyl-tin hydride

: 84666-32-0
C₆H₅CH₂CH₂C(Sn(C₄H₉)3)CH₂O

: 109669-46-7,84666-31-9,243662-95-5
<(1Z)-3-(benzyloxy)-1-propen-1-yl>tributylstannate

: 84666-31-9,109669-46-7,243662-95-5
<(1E)-3-(benzyloxy)-1-propen-1-yl>tributylstannate

Guidance literature:: With hydroquinone; tris(t-butyl isocyanide)tricarbonylmolybdenum(O); In tetrahydrofuran; alkyne dissolved in THF; catalyst and hydroquinone added; mixt warmed to60°C; Bu3SnH added; soln. stirred at 60°C for 12 h; solvent evapd. (vac.); purifn. by chromy. (eluent petrolether-EtOAc-NEt3);
DOI:10.1016/S0022-328X(01)01309-2