Phosphinic azide, (1,1-dimethylethyl)phenyl-

Base Information

• Chemical Name: Phosphinic azide, (1,1-dimethylethyl)phenyl-
• CAS No.: 84718-90-1
• Molecular Formula: C10H14N3OP
• Molecular Weight: 223.214
• Mol file: 84718-90-1.mol

Synonyms:

Chemical Property of Phosphinic azide, (1,1-dimethylethyl)phenyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phosphinic azide, (1,1-dimethylethyl)phenyl-

There total 1 articles about Phosphinic azide, (1,1-dimethylethyl)phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tert-butylphenylphosphinic acid chloride (4923-85-7) → t-butyl(phenyl)phosphinic azide (84718-90-1)

Guidance literature:

With sodium azide; In acetonitrile; for 27h; Ambient temperature;

DOI:10.1016/0040-4020(82)80195-6

Reference yield: 32.0%

dimethylsulfide (75-18-3) + t-butyl(phenyl)phosphinic azide (84718-90-1) → (+/-)-P-t-butyl-P-phenyl-N-phosphoramidate (51028-18-3) + N-dimethylsulphilimine (84718-93-4) + N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide (84718-94-5)

Guidance literature:

for 8h; Irradiation;

Reference yield: 21.0%

t-butyl(phenyl)phosphinic azide (84718-90-1) → (+/-)-P-t-butyl-P-phenyl-N-phosphoramidate (51028-18-3) + N-dimethylsulphilimine (84718-93-4) + N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide (84718-94-5)

Guidance literature:

With dimethylsulfide; for 8h; Irradiation;

upstream raw materials:

tert-butylphenylphosphinic acid chloride

Downstream raw materials:

(+/-)-P-t-butyl-P-phenyl-N-phosphoramidate

methyl N-phenyl-tert-butylphosphonoamidate

methyl N-t-butyl-P-phenylphosphonamidate

t-butylphenylphosphinic N-methoxyamide