84718-94-5

Basic information

• Product Name: N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide
• CAS NO: 84718-94-5
• Molecular Weight: 257.337
• Mol File: 84718-94-5.mol

Chemical Properties

• CAS DataBase Reference: N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide(84718-94-5)
• EPA Substance Registry System: N-(methylthiomethyl)-t-butyl(phenyl)phosphinic amide(84718-94-5)

Safety Data

• Hazardous Substances Data: 84718-94-5(Hazardous Substances Data)

Upstream product

• 84718-90-1 t-butyl(phenyl)phosphinic azide 
• 75-18-3 dimethylsulfide 
• 67-56-1 methanol 

Relevant articles and documents

DIMETHYLSULPHIDE AS A NITRENE TRAP IN THE PHOTOLYSIS OF SOME PHOSPHINIC AZIDES

When PhRP(O)N3 (R=Ph or t-Bu) is photolysed in dimethylsulphide substantial amounts (22-32percent) of PhRP(O)N:SMe2 and PhRP(O)NHCH2SMe are produced and rearrangement is less important than in benzene.

Photolysis of Diphenyl- and t-Butyl(phenyl)-phosphinic Azides: Dimethyl Sulphide as a Nitrene Trap, and Its Influence on the Curtius-like Rearrangement

Photolysis of Ph2P(O)N3 in benzene containing MeOH gives a high yield (72percent) of the phosphonamidate PhP(O)(OMe)NHPh (3) resulting from Curtius-like rearrangement.When some of the benzene solvent is replaced by Me2S the yield of the rearrangement prod