Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-

Base Information

Chemical Name:Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-
CAS No.:84750-90-3
Molecular Formula:C9H8F2O
Molecular Weight:170.159
Hs Code.:
DSSTox Substance ID:DTXSID30445304
Nikkaji Number:J1.302.107D

Synonyms:84750-90-3;Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-;3-(2,2-Difluoroethenyl)anisole;DTXSID30445304;beta,beta-Difluoro-3-methoxystyrene;1,1-Difluoro-2-(3-methoxyphenyl)ethene

Suppliers and Price of Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-

Chemical Property:

XLogP3:3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:170.05432120
Heavy Atom Count:12
Complexity:164

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=CC=CC(=C1)C=C(F)F

Technology Process of Benzene, 1-(2,2-difluoroethenyl)-3-methoxy-

There total 10 articles about Benzene, 1-(2,2-difluoroethenyl)-3-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 1895-39-2
sodium chlorodifluoroacetate

: 591-31-1
3-methoxy-benzaldehyde

: 84750-90-3
1-(2,2-difluorovinyl)-3-methoxybenzene

Guidance literature:: With triphenylphosphine; In N,N-dimethyl-formamide; at 100 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jacs.7b08343

Reference yield: 70.0%

: 10365-98-7,1107579-37-2
3-methoxyphenylboronic acid

: 2236129-81-8
trifluoroacetaldehyde N-triftosylhydrazone

: 84750-90-3
1-(2,2-difluorovinyl)-3-methoxybenzene

Guidance literature:: With ammonium chloride; lithium hydroxide; at 100 ℃; for 12h; Inert atmosphere;
DOI:10.1021/acs.orglett.9b03740

Reference yield: 62.0%

: 108087-83-8
[(3-methoxyphenyl)methylidene]hydrazine

: C₅H₉BrF₂Si

: 84750-90-3
1-(2,2-difluorovinyl)-3-methoxybenzene

Guidance literature:: [(3-methoxyphenyl)methylidene]hydrazine; With manganese(IV) oxide; magnesium sulfate; In 1,2-dichloro-ethane; at 0 ℃; for 2h;

C₅H₉BrF₂Si; With tetrabutylammomium bromide; at 70 ℃; chemoselective reaction;
DOI:10.1002/anie.201509711