1-Cyclohexene-1-carboxylic acid, 3-[2,6-bis(acetyloxy)-4-pentylphenyl]-4-(1-methylethenyl)-, (3S,4S)-

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Chemical Name:1-Cyclohexene-1-carboxylic acid, 3-[2,6-bis(acetyloxy)-4-pentylphenyl]-4-(1-methylethenyl)-, (3S,4S)-
CAS No.:847949-34-2
Molecular Formula:C25H32O6
Molecular Weight:428.525
Hs Code.:

Synonyms:

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Chemical Property of 1-Cyclohexene-1-carboxylic acid, 3-[2,6-bis(acetyloxy)-4-pentylphenyl]-4-(1-methylethenyl)-, (3S,4S)-

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Technology Process of 1-Cyclohexene-1-carboxylic acid, 3-[2,6-bis(acetyloxy)-4-pentylphenyl]-4-(1-methylethenyl)-, (3S,4S)-

There total 7 articles about 1-Cyclohexene-1-carboxylic acid, 3-[2,6-bis(acetyloxy)-4-pentylphenyl]-4-(1-methylethenyl)-, (3S,4S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 847949-33-1
Acetic acid 3-acetoxy-2-((1S,6S)-3-formyl-6-isopropenyl-cyclohex-2-enyl)-5-pentyl-phenyl ester

: 847949-34-2
(3S,4S)-3-(2,6-Diacetoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enecarboxylic acid

Guidance literature:: With sodium chlorite; potassium dihydrogenphosphate; 2-methyl-but-2-ene; at 20 ℃; for 5h;
DOI:10.1039/b416943c

Reference yield:

: 247227-98-1,22198-90-9
(1S,2S)-2',6'-dimethoxy-5-methyl-4'-pentyl-2-(prop-1-en-2-yl)-1,2,3,4-tetrahydro-1,1'-biphenyl

: 847949-34-2
(3S,4S)-3-(2,6-Diacetoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enecarboxylic acid

Guidance literature:: Multi-step reaction with 7 steps

1: 66 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 0.5 h / 0 °C

2: 97 percent / BuLi; N-cyclohexylisopropylamine; methylmagnesium bromide / toluene; diethyl ether / 2 h / 40 °C

3: 42 percent / MeMgI / diethyl ether / 0.75 h / 210 °C

4: 100 percent / pyridine / 18 h / 20 °C

5: 90 percent / TMSBr; ZnI₂ / CH₂Cl₂ / 4 h / 20 °C

6: 32 percent / 18-crown-6; K₂CrO₄; 4 Angstroem molecular sieves / hexamethylphosphoric acid triamide / 2 h / 110 °C

7: 85 percent / NaClO₂; 2-methyl-2-butene; aq. KH₂PO₄ / 5 h / 20 °C

With pyridine; sodium chlorite; potassium chromate; potassium dihydrogenphosphate; methyl magnesium iodide; n-butyllithium; 2-methyl-but-2-ene; 18-crown-6 ether; trimethylsilyl bromide; 4 A molecular sieve; N-cyclohexylisopropylamine; methylmagnesium bromide; 3-chloro-benzenecarboperoxoic acid; zinc(II) iodide; In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; dichloromethane; toluene;
DOI:10.1039/b416943c

Reference yield:

: 847949-24-0
(1R,4S,5S,6S)-5-(2,6-Dimethoxy-4-pentyl-phenyl)-4-isopropenyl-1-methyl-7-oxa-bicyclo[4.1.0]heptane

: 847949-34-2
(3S,4S)-3-(2,6-Diacetoxy-4-pentyl-phenyl)-4-isopropenyl-cyclohex-1-enecarboxylic acid

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / BuLi; N-cyclohexylisopropylamine; methylmagnesium bromide / toluene; diethyl ether / 2 h / 40 °C

2: 42 percent / MeMgI / diethyl ether / 0.75 h / 210 °C

3: 100 percent / pyridine / 18 h / 20 °C

4: 90 percent / TMSBr; ZnI₂ / CH₂Cl₂ / 4 h / 20 °C

5: 32 percent / 18-crown-6; K₂CrO₄; 4 Angstroem molecular sieves / hexamethylphosphoric acid triamide / 2 h / 110 °C

6: 85 percent / NaClO₂; 2-methyl-2-butene; aq. KH₂PO₄ / 5 h / 20 °C

With pyridine; sodium chlorite; potassium chromate; potassium dihydrogenphosphate; methyl magnesium iodide; n-butyllithium; 2-methyl-but-2-ene; 18-crown-6 ether; trimethylsilyl bromide; 4 A molecular sieve; N-cyclohexylisopropylamine; methylmagnesium bromide; zinc(II) iodide; In N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; dichloromethane; toluene;
DOI:10.1039/b416943c