N-(Triphenylphosphoranylidene)-m-toluidine

Base Information

• Chemical Name: N-(Triphenylphosphoranylidene)-m-toluidine
• CAS No.: 35843-75-5
• Molecular Formula: C25H22 N P
• Molecular Weight: 367.43
• European Community (EC) Number: 252-752-6
• NSC Number: 158470
• DSSTox Substance ID: DTXSID10189390
• Nikkaji Number: J319.544I
• Wikidata: Q83061468
• Mol file: 35843-75-5.mol

Synonyms:35843-75-5;N-(Triphenylphosphoranylidene)-m-toluidine;EINECS 252-752-6;3-Methyl-N-(triphenylphosphoranylidene)aniline;NSC158470;C18H28NO.I;DTXSID10189390;AKOS024430179;NSC 158470;NSC-158470;(3-methylphenyl)imino-triphenyl-lambda5-phosphane;3-Methyl-N-(triphenylphosphoranylidene)benzenamine;N-(M-TOLYL)-P,P,P-TRIPHENYLPHOSPHINE IMIDE

Chemical Property of N-(Triphenylphosphoranylidene)-m-toluidine

Chemical Property:

• Vapor Pressure: 1.08E-10mmHg at 25°C
• Boiling Point: 527.6°Cat760mmHg
• Flash Point: 272.9°C
• PSA: 22.17000
• Density: 1.06g/cm³
• LogP: 5.80420
• XLogP3: 6.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 367.148986704
• Heavy Atom Count: 27
• Complexity: 442

Purity/Quality:

99% ^*data from raw suppliers

N-(M-TOLYL)-P,P,P-TRIPHENYLPHOSPHINE IMIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC(=CC=C1)N=P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of N-(Triphenylphosphoranylidene)-m-toluidine

There total 3 articles about N-(Triphenylphosphoranylidene)-m-toluidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylphosphine (603-35-0) + 1-amino-3-methylbenzene (108-44-1) → N-triphenylphosphoranylidene-m-toluidine (35843-75-5)

Guidance literature:

triphenylphosphine; With bromine; In benzene; at -5 - 20 ℃; for 1.33333h; Inert atmosphere;

1-amino-3-methylbenzene; With triethylamine; In benzene; Inert atmosphere; Reflux;

DOI:10.1002/adsc.201000469

Reference yield:

1-azido-3-methylbenzene (4113-72-8) + triphenylphosphine (603-35-0) → N-triphenylphosphoranylidene-m-toluidine (35843-75-5)

Guidance literature:

In 1,2-dichloro-ethane; at 50 ℃;

DOI:10.1021/jo702733h

Reference yield:

→ N-triphenylphosphoranylidene-m-toluidine (35843-75-5)

Guidance literature:

/BRN= 2955405/;

upstream raw materials:

1-azido-3-methylbenzene

triphenylphosphine

1-amino-3-methylbenzene

Downstream raw materials:

N,N'-bis(m-methylphenyl)carbodiimide

C₃₀H₂₁N₄P

C₂₅H₂₃NO₃

C₂₅H₂₃NO₃