Piperyline

Base Information

Chemical Name:Piperyline
CAS No.:25924-78-1
Molecular Formula:C16H17 N O3
Molecular Weight:271.316
Hs Code.:2934999090
UNII:GV0493SM38
DSSTox Substance ID:DTXSID20180595
Nikkaji Number:J17.360F,J47.725G
Wikidata:Q27108470
Metabolomics Workbench ID:43798
ChEMBL ID:CHEMBL1087296
Mol file:25924-78-1.mol

Synonyms:(2E,4E)-5-(1,3-Benzodioxol-5-yl)-1-(1-pyrrolidinyl)-2,4-pentadien-1-one;1-piperoylpyrrolidine;piperyline

Suppliers and Price of Piperyline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Piperyline analytical standard
10mg
$ 874.00

Total 2 raw suppliers

Chemical Property of Piperyline

Chemical Property:

Vapor Pressure:1.53E-09mmHg at 25°C
Boiling Point:484.5°Cat760mmHg
Flash Point:246.8°C
PSA：38.77000
Density:1.246g/cm³
LogP:2.54500
XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:271.12084340
Heavy Atom Count:20
Complexity:399

Purity/Quality:

98%Min ^*data from raw suppliers

Piperyline analytical standard ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1CCN(C1)C(=O)C=CC=CC2=CC3=C(C=C2)OCO3
Isomeric SMILES:C1CCN(C1)C(=O)/C=C/C=C/C2=CC3=C(C=C2)OCO3
Description A further minor alkaloid found in Piper nigrum, this base may be recrystallized from Et20 when it yields long, slender needles. The ultraviolet spectrum has absorption maxima at 245,261,309 and 343 mil. The configuration about both of the double bonds in the side chain is trans. The structure given above has been confirmed by synthesis.

Technology Process of Piperyline

There total 1 articles about Piperyline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6190-46-1,89812-63-5
methyl (2E,4E)-5-(benzo[d][1,3]dioxol-5-yl)penta-2,4-dienoate

: 25924-78-1
piperylin

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydroxide / methanol / 8 h / 20 °C

2: O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 8 h / 20 °C

With O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate; N-ethyl-N,N-diisopropylamine; sodium hydroxide; In methanol; N,N-dimethyl-formamide;
DOI:10.1080/14756366.2021.1896500