Molybdenum pentafluoride

Base Information

• Chemical Name: Molybdenum pentafluoride
• CAS No.: 13819-84-6
• Molecular Formula: F₅Mo
• Molecular Weight: 190.932
• DSSTox Substance ID: DTXSID10160528
• Wikipedia: Molybdenum pentafluoride
• Wikidata: Q4493212
• Mol file: 13819-84-6.mol

Synonyms:Molybdenum pentafluoride;13819-84-6;MoF5;pentafluoromolybdenum;molybdenum(5+) fluoride;[MoF5];Molybdenum fluoride (MoF5);CHEBI:30711;DTXSID10160528;Q4493212

Chemical Property of Molybdenum pentafluoride

Chemical Property:

• Melting Point: 67°C
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: -14.98000
• Water Solubility.: reac H2O [CRC10]
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 192.897419
• Heavy Atom Count: 6
• Complexity: 37.1

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: F[Mo](F)(F)(F)F

Technology Process of Molybdenum pentafluoride

There total 7 articles about Molybdenum pentafluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

molybdenum(VI) fluoride (7783-77-9) + phosphorus trichloride (7719-12-2,52843-90-0) → molybdenum(V) fluoride (13819-84-6,194303-41-8) + phosphorus pentafluoride (7647-19-0,874483-74-6) + chlorine (7782-50-5) + trifluorophosphane (7783-55-3) + molybdenum(IV) chloride (13320-71-3)

Guidance literature:

In not given; react. with an excess of MoF6 forming PF3, MoCl5 and Cl2; react. of MoCl5 forming MoCl4 and Cl2; further react. of MoF6 with PF3 forming PF5 and MoF5;;

DOI:10.1016/0022-1902(62)80185-7

Reference yield:

oxygen (80937-33-3) + fluorine (7782-41-4) + molybdenum (7439-98-7) → molybdenum(VI) fluoride (7783-77-9) + molybdenum tetrafluoride (23412-45-5) + molybdenum(V) fluoride (13819-84-6,194303-41-8) + molybdenum pentafluoride trimer + molybdenum oxotetrafluoride (14459-59-7,52049-90-8)

Guidance literature:

In gas; reacted in gas phase at 100-1100°C using F2 contg. ca. 1% O2; further products; not isolated, detected by IR in Ar matrice;

Reference yield:

nitrogen trifluoride (7783-54-2) + molybdenum (7439-98-7) → molybdenum(VI) fluoride (7783-77-9) + molybdenum(V) fluoride (13819-84-6,194303-41-8)

Guidance literature:

byproducts: N2; NF3 redn. by molybdenum incandescent filament in reaction vessel withoutinternal screen (pressure 0.2-0.4 atm, filament temp. 350-400°C, cooling. temp. 100-150°C); vac. distn. at 60°C; X-ray diffraction, gas chromy.;

upstream raw materials:

molybdenum(VI) fluoride

phosphorus trichloride

nitrogen trifluoride

molybdenum

Downstream raw materials:

molybdenum(VI) fluoride

Refernces

• 1、 Osin,Davlyatshin,Ogden. "Infrared spectra of the products of interaction of tungsten and Molybdenum with fluorine isolated in solid argon". . p. 237 - 245. Retrieved 2007/10/03.