Dimethyl (pentafluorophenyl)boronate

Base Information

Chemical Name:Dimethyl (pentafluorophenyl)boronate
CAS No.:848609-02-9
Molecular Formula:C8H6BF5O2
Molecular Weight:239.937
Hs Code.:
DSSTox Substance ID:DTXSID60593221
Nikkaji Number:J2.252.147K
Wikidata:Q82487664

Synonyms:848609-02-9;SCHEMBL6680335;DTXSID60593221;Dimethyl (pentafluorophenyl)boronate

Suppliers and Price of Dimethyl (pentafluorophenyl)boronate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Dimethyl (pentafluorophenyl)boronate

Chemical Property:

Boiling Point:191.0±40.0 °C(Predicted)
PSA：18.46000
Density:1.32±0.1 g/cm3(Predicted)
LogP:1.37010
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:7
Rotatable Bond Count:3
Exact Mass:240.0381004
Heavy Atom Count:16
Complexity:215

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C(=C(C(=C1F)F)F)F)F)(OC)OC

Technology Process of Dimethyl (pentafluorophenyl)boronate

There total 3 articles about Dimethyl (pentafluorophenyl)boronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: lithium pentafluorophenyltrimethoxyborate

: 848609-02-9
dimethyl pentafluorophenylboronate

: 121-43-7,63156-11-6
Trimethyl borate

Guidance literature:: In neat (no solvent); byproducts: C6F5H; under Ar, teflon-perfluoropropylene block copolymer vessel evacuated at 3E-2 hPa, 150-170 °C for 3 h; distn., yields were determined by (19)F and (11)B NMR;
DOI:10.1002/zaac.200500083

Reference yield: 48.0%

: lithium pentafluorophenyltrimethoxyborate

: 848609-02-9
dimethyl pentafluorophenylboronate

Guidance literature:: With Me₃SiCl; In dichloromethane; byproducts: C6F5H, LiCl, Me3SiOMe; under Ar, perfluoro-ethene/perfluoro-propene block copolymer vessel, 1.6equiv. of Me3SiCl, stirring at 25 °C for 1 h; not isolated yield, determined with (19)F NMR;
DOI:10.1002/zaac.200500083

Reference yield:

: 121-43-7,63156-11-6
Trimethyl borate

: 344-04-7
bromopentafluorobenzene

: 848609-02-9
dimethyl pentafluorophenylboronate

Guidance literature:: bromopentafluorobenzene; With iodine; magnesium; In tetrahydrofuran;

Trimethyl borate; In tetrahydrofuran; at -78 ℃; for 1h; Further stages.;
DOI:10.1016/j.jfluchem.2007.07.012