p-Trichlorosilylbiphenyl

Base Information

• Chemical Name: p-Trichlorosilylbiphenyl
• CAS No.: 18030-61-0
• Molecular Formula: C12H9Cl3Si
• Molecular Weight: 287.648
• Hs Code.: 2931900090
• DSSTox Substance ID: DTXSID10170945
• Nikkaji Number: J644.084C
• Wikidata: Q83040963
• Mol file: 18030-61-0.mol

Synonyms:p-Trichlorosilylbiphenyl;18030-61-0;trichloro-(4-phenylphenyl)silane;[1,1'-biphenyl]-4-yltrichlorosilane;1,1'-Biphenyl, 4-(trichlorosilyl)-;Silane, [1,1'-biphenyl]-4-yltrichloro-;p-Xenyltrichlorosilane;4-trichlorosilylbiphenyl;4-(trichlorosilyl)-biphenyl;SCHEMBL1941691;DTXSID10170945;4-(trichlorosilyl)-1,1'-biphenyl;MFCD00185795;AKOS028108584;{[1,1'-biphenyl]-4-yl}trichlorosilane;AS-61627

Chemical Property of p-Trichlorosilylbiphenyl

Chemical Property:

• Vapor Pressure: 0.000387mmHg at 25°C
• Boiling Point: 327.4°Cat760mmHg
• Flash Point: 163°C
• PSA: 0.00000
• Density: 1.3g/cm³
• LogP: 4.21590
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 285.953910
• Heavy Atom Count: 16
• Complexity: 213

Purity/Quality:

99% ^*data from raw suppliers

[1,1'-Biphenyl]-4-yltrichlorosilane 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=C(C=C2)[Si](Cl)(Cl)Cl

Technology Process of p-Trichlorosilylbiphenyl

There total 6 articles about p-Trichlorosilylbiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

4-bromo-1,1'-biphenyl (92-66-0) → 4-(trichlorosilyl)biphenyl (18030-61-0)

Guidance literature:

With tetrachlorosilane; magnesium; In tetrahydrofuran; at -90 - 20 ℃; for 24h;

DOI:10.1039/b515727g

Reference yield:

biphenyl (92-52-4,1594-86-1) → biphenyl-3-yl-trichloro-silane (14555-65-8) + 4-(trichlorosilyl)biphenyl (18030-61-0)

Guidance literature:

With trichlorosilane; boron trichloride; at 270 ℃;

DOI:10.1021/ie50590a032

Reference yield:

2-chloro-1,1'-biphenyl (2051-60-7,108321-69-3) → biphenyl-3-yl-trichloro-silane (14555-65-8) + 4-(trichlorosilyl)biphenyl (18030-61-0)

Guidance literature:

With trichlorosilane; at 370 ℃;

DOI:10.1021/ie50590a032

upstream raw materials:

biphenyl

2-chloro-1,1'-biphenyl

4'-biphenyl chloride

4-bromo-1,1'-biphenyl