9-tert-butyl 2-methyl 2-(phenylselanyl)-9-azabicyclo[4.2.1]nonane-2,9-dicarboxylate

Base Information

• Chemical Name: 9-tert-butyl 2-methyl 2-(phenylselanyl)-9-azabicyclo[4.2.1]nonane-2,9-dicarboxylate
• CAS No.: 125736-09-6
• Molecular Formula: C₂₁H₂₉NO₄Se
• Molecular Weight: 438.426
• Mol file: 125736-09-6.mol

Synonyms:9-Azabicyclo[4.2.1]nonane-2,9-dicarboxylicacid, 2-(phenylseleno)-, 9-(1,1-dimethylethyl) 2-methyl ester, exo- (9CI);9-Azabicyclo[4.2.1]nonane-2,9-dicarboxylic acid, 2-(phenylseleno)-,9-(1,1-dimethylethyl) 2-methyl ester, exo-(?à)-

Chemical Property of 9-tert-butyl 2-methyl 2-(phenylselanyl)-9-azabicyclo[4.2.1]nonane-2,9-dicarboxylate

Chemical Property:

• Vapor Pressure: 6.37E-10mmHg at 25°C
• Boiling Point: 494.6°Cat760mmHg
• Flash Point: 252.9°C
• Density: g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-tert-butyl 2-methyl 2-(phenylselanyl)-9-azabicyclo[4.2.1]nonane-2,9-dicarboxylate

There total 1 articles about 9-tert-butyl 2-methyl 2-(phenylselanyl)-9-azabicyclo[4.2.1]nonane-2,9-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenylselenyl bromide (34837-55-3) + 9-Aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester (125736-06-3,125736-07-4,129099-02-1,129170-27-0) → 2-Phenylselanyl-9-aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester (125736-08-5,125736-09-6)

Guidance literature:

With n-butyllithium; diphenyl diselenide; diisopropylamine; Multistep reaction;

DOI:10.1021/jo00296a050

Reference yield: 74.0%

2-Phenylselanyl-9-aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester (125736-08-5,125736-09-6) → 9-Aza-bicyclo[4.2.1]non-2-ene-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester (125736-10-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; a) 0 deg C, 45 min, b) r.t., 30 min;

DOI:10.1021/jo00296a050

upstream raw materials:

Phenylselenyl bromide

9-Aza-bicyclo[4.2.1]nonane-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester

Downstream raw materials:

9-Aza-bicyclo[4.2.1]non-2-ene-2,9-dicarboxylic acid 9-tert-butyl ester 2-methyl ester