2,2'-Bipyridine, 6-(4-methoxyphenyl)-

Base Information

• Chemical Name: 2,2'-Bipyridine, 6-(4-methoxyphenyl)-
• CAS No.: 850009-24-4
• Molecular Formula: C17H14N2O
• Molecular Weight: 262.311
• Mol file: 850009-24-4.mol

Synonyms:

Chemical Property of 2,2'-Bipyridine, 6-(4-methoxyphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2'-Bipyridine, 6-(4-methoxyphenyl)-

There total 1 articles about 2,2'-Bipyridine, 6-(4-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

2-bromo-6-(pyridin-2-yl)pyridine (10495-73-5) + 4-methoxyphenylboronic acid (5720-07-0) → 6-(4-methoxyphenyl)-2,2′-bipyridine (850009-24-4)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In toluene; at 100 ℃; Inert atmosphere;

DOI:10.1002/anie.201914864

Reference yield: 84.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 6-(4-methoxyphenyl)-2,2′-bipyridine (850009-24-4) + tricyclohexylphosphine (2622-14-2) → [copper(I)(MeO-CNN)(tricyclohexylphosphine)]BF4 (1206595-36-9)

Guidance literature:

In dichloromethane; mixt. of (Cu(CH3CN)4)BF4 and MeO-CNN in CH2Cl2 stirred under N2 at room temp. for 2 h, PCy3 added, stirred for 2 h; vapor diffusion with diethyl ether, elem. anal.;

DOI:10.1016/j.ica.2009.10.010

Reference yield: 82.0%

tetrakis(acetonitrile)copper(I)tetrafluoroborate + 6-(4-methoxyphenyl)-2,2′-bipyridine (850009-24-4) → copper(I) bis(6-(4-methoxy)phenyl-2,2'-bipyridine) tetrafluoroborate (850009-19-7)

Guidance literature:

In dichloromethane; (N2), Cu complex and ligand (1:2) in CH2Cl2 stirred at room temp. for 2 h; evapd., recrystd.(Et2O diffusion into CH2Cl2 soln.), elem. anal.;

DOI:10.1016/j.ica.2007.02.007

upstream raw materials:

2-bromo-6-(pyridin-2-yl)pyridine

4-methoxyphenylboronic acid

Downstream raw materials:

copper(I) bis(6-(4-methoxy)phenyl-2,2'-bipyridine) tetrafluoroborate

[copper(I)(MeO-CNN)(tricyclohexylphosphine)]BF₄