4-Chlorobenzenediazonium hexafluorophosphate

Base Information

• Chemical Name: 4-Chlorobenzenediazonium hexafluorophosphate
• CAS No.: 1582-27-0
• Molecular Formula: C6H4ClN2+
• Molecular Weight: 284.528
• European Community (EC) Number: 216-429-3
• Mol file: 1582-27-0.mol

Synonyms:4-Chlorobenzenediazonium hexafluorophosphate;1582-27-0;4-chlorobenzenediazonium;hexafluorophosphate;4-Chlorobenzenediazonium hexafluorophosphate(1-);C6H4ClN2.F6P;C6-H4-Cl-N2.F6-P;JOLVAGIWTVZCNF-UHFFFAOYSA-N;EINECS 216-429-3;p-Chlorobenzenediazonium hexafluorophosphate;p-chlorobenzenediazonium hexa-fluorophosphate;4-chlorobenzene-diazonium hexafluorophosphate;FT-0618172;Benzenediazonium, 4-chloro-, hexafluorophosphate(1-);Benzenediazonium, p-chloro-, hexafluorophosphate(1-);Benzenediazonium, 4-chloro-, hexafluorophosphate(1-) (1:1)

Chemical Property of 4-Chlorobenzenediazonium hexafluorophosphate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 41.74000
• Density: g/cm³
• LogP: 6.20698
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 283.9704818
• Heavy Atom Count: 16
• Complexity: 192

Purity/Quality:

98%Min ^*data from raw suppliers

4-CHLOROBENZENEDIAZONIUM HEXAFLUOROPHOSPHATE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 20/21/22-34
• Safety Statements: 26-27-28-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC(=CC=C1[N+]#N)Cl.F[P-](F)(F)(F)(F)F

Technology Process of 4-Chlorobenzenediazonium hexafluorophosphate

There total 1 articles about 4-Chlorobenzenediazonium hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

4-chloro-aniline (106-47-8) → 4-chlorobenzene-diazonium hexafluorophosphate (1582-27-0)

Guidance literature:

4-chloro-aniline; With hexafluorophosphoric acid; In water; at 20 ℃; for 0.0333333h; Inert atmosphere;

With sodium nitrite; In water; at 0 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/acs.orglett.7b01148

Reference yield: 92.5%

tetracarbonyl(cis-1,2-bis(diphenylphosphino)ethylene)(1,3-propanedithiolato)diiron(I) (932706-71-3,950906-88-4) + 4-chlorobenzene-diazonium hexafluorophosphate (1582-27-0) → [Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6 (1370525-58-8)

Guidance literature:

In dichloromethane; dissolving mixt. of iron compd. and phenyldiazonium salt in CH2Cl2 at 0°C, stirring for 45 min; addn. of hexane, extn. (CH2Cl2), filtration through celite, addn. of hexane, isolation of ppt., elem. anal.;

DOI:10.1021/om300107s

Reference yield: 62.0%

4-chlorobenzene-diazonium hexafluorophosphate (1582-27-0) → 1-Chloro-4-fluorobenzene (352-33-0)

Guidance literature:

With boron trifluoride diethyl etherate; at 120 - 125 ℃; for 1h;

DOI:10.1080/00397919308011253

upstream raw materials:

4-chloro-aniline

Downstream raw materials:

1-Chloro-4-fluorobenzene

Phenyl-p-chlorphenylchloroniumtetraphenylborat

[Fe2(1,3-propanedithiolate)(CO)4(cis-Ph2PCHCHPPh2)(μ-η1:η1-p-chlorophenyldiazonium)]PF6

1-allyl-4-chlorobenzene

Refernces