Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-

Base Information

Chemical Name:Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-
CAS No.:850594-21-7
Molecular Formula:C18H34ClN2O5P
Molecular Weight:424.905
Hs Code.:

Hydrazinecarboxylic acid,
[2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-,
(1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-

Synonyms:

Suppliers and Price of Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)-

There total 2 articles about Hydrazinecarboxylic acid, [2-chloro-2-(diethoxyphosphinyl)-1-methylethylidene]-, (1R,2S,5R)-5-methyl-2-(1-methylethyl)cyclohexyl ester, (2E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: diethyl [(2-(-)-menthyloxycarbonylhydrazono)propyl]phosphonate

: 850594-21-7
diethyl [1-chloro-2-((-)-menthyloxycarbonylhydrazono)propyl]phosphonate

Guidance literature:: With N-chloro-succinimide; In tetrachloromethane; at 20 ℃; for 16h;
DOI:10.1016/j.tet.2005.01.081

Reference yield:

: 14602-86-9,7635-53-2
(1R,2S,5R)-menthyl chloroformate

: 850594-21-7
diethyl [1-chloro-2-((-)-menthyloxycarbonylhydrazono)propyl]phosphonate

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrazine hydrate; triethylbenzylammonium chloride; K₂CO₃ / CH₂Cl₂; CCl₄

2.1: CHCl₃ / Heating

2.2: 43 percent / N-chlorosuccinimide / CCl₄ / 20 °C

With N-benzyl-N,N,N-triethylammonium chloride; potassium carbonate; hydrazine hydrate; In tetrachloromethane; dichloromethane; chloroform;
DOI:10.1016/j.tetlet.2004.03.192

Reference yield: 92.0%

: 459-73-4
GlyOEt*HCl

: 850594-21-7
diethyl [1-chloro-2-((-)-menthyloxycarbonylhydrazono)propyl]phosphonate

: ethyl [1-(diethoxyphosphoryl)-2-((-)-menthyloxycarbonylhydrazono)propylamino]acetate

Guidance literature:: diethyl [1-chloro-2-((-)-menthyloxycarbonylhydrazono)propyl]phosphonate; With triethylamine; In dichloromethane; at 20 ℃;

GlyOEt*HCl; In dichloromethane; at 20 ℃; Further stages.;
DOI:10.1016/j.tetlet.2004.03.192