Acridinium, 10-methyl-, hexafluorophosphate(1-)

Base Information

• Chemical Name: Acridinium, 10-methyl-, hexafluorophosphate(1-)
• CAS No.: 85191-66-8
• Molecular Formula: C14H12N.F6P
• Molecular Weight: 339.22
• Mol file: 85191-66-8.mol

Synonyms:

Chemical Property of Acridinium, 10-methyl-, hexafluorophosphate(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acridinium, 10-methyl-, hexafluorophosphate(1-)

There total 2 articles about Acridinium, 10-methyl-, hexafluorophosphate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

9-benzyl-10-methyl-9,10-dihydroacridine (150787-21-6) → N-methylacridinium hexafluorophosphate (85191-66-8) + C21H18N(1+)*F6P(1-) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With tris(1,10-phenanthroline)iron(III) tris(hexafluorophosphate); In acetonitrile; at 24.9 ℃; Rate constant; Product distribution; also in reaction with Fe(ClO₄)3; other 10-methyl-9,10-dihydroacridines derivatives;

Reference yield:

2-(10-Methyl-9,10-dihydro-acridin-9-yl)-propionic acid ethyl ester (134924-36-0) → ethyl 2-hydroxypropionate (97-64-3,2676-33-7) + N-methylacridinium hexafluorophosphate (85191-66-8) + C19H20NO2(1+)*F6P(1-)

Guidance literature:

With tris(1,10-phenanthroline)iron(III) tris(hexafluorophosphate); In acetonitrile; at 24.9 ℃; Rate constant;

Reference yield: 85.0%

(η5-pentamethylcyclopentadienyl)RuH(Ph2P2CH2) + N-methylacridinium hexafluorophosphate (85191-66-8) → C5(CH3)5(1-)*CH2(P(C6H5)2)2*Ru(2+)*N2*PF6(1-)={(C5(CH3)5)(CH2(P(C6H5)2)2)Ru(N2)}PF6 (154204-35-0)

Guidance literature:

With nitrogen; In tetrahydrofuran; byproducts: N-methyl-5,10-dihydroacridine; under N2 at 23°C in THF; addn. of Et2O; elem. anal.;

DOI:10.1021/ja00084a063

upstream raw materials:

9-benzyl-10-methyl-9,10-dihydroacridine

2-(10-Methyl-9,10-dihydro-acridin-9-yl)-propionic acid ethyl ester

Downstream raw materials:

C₅(CH₃)5^(1-)*CH₂(P(C₆H₅)2)2*Ru⁽²⁺⁾*N₂*PF₆^(1-)={(C₅(CH₃)5)(CH₂(P(C₆H₅)2)2)Ru(N₂)}PF₆

hydrogen