4-Diphenylphosphorylbutyl(diphenyl)phosphane

Base Information

Chemical Name:4-Diphenylphosphorylbutyl(diphenyl)phosphane
CAS No.:85686-00-6
Molecular Formula:C28H28OP2
Molecular Weight:442.46900
Hs Code.:2902909090
DSSTox Substance ID:DTXSID00402782
Nikkaji Number:J1.011.004A
Wikidata:Q72445387
Mol file:85686-00-6.mol

Synonyms:1,4-Bis(diphenylphosphino)butane monooxide;85686-00-6;4-diphenylphosphorylbutyl(diphenyl)phosphane;SCHEMBL3263862;DTXSID00402782;OGJJWCHXAGSHLL-UHFFFAOYSA-N;Ph2PCH2CH2CH2CH2P(O)Ph2;AKOS015915775;4-(Diphenylphosphino)butyldiphenylphosphine oxide;1,4-Bis(diphenylphosphino)butane monooxide, 97%;[4-(Diphenylphosphanyl)butyl](oxo)diphenyl-lambda~5~-phosphane

Suppliers and Price of 4-Diphenylphosphorylbutyl(diphenyl)phosphane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
1,4-Bis(diphenylphosphino)butane monooxide 97%
5g
$ 439.00

Sigma-Aldrich
1,4-Bis(diphenylphosphino)butane monooxide 97%
1g
$ 109.00

American Custom Chemicals Corporation
1,4-BIS(DIPHENYLPHOSPHINO)BUTANE MONOOXIDE 95.00%
5G
$ 1247.32

American Custom Chemicals Corporation
1,4-BIS(DIPHENYLPHOSPHINO)BUTANE MONOOXIDE 95.00%
1G
$ 728.26

Total 8 raw suppliers

Chemical Property of 4-Diphenylphosphorylbutyl(diphenyl)phosphane

Chemical Property:

Melting Point:183-188oC(lit.)
PSA：40.47000
LogP:5.91360
XLogP3:6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:9
Exact Mass:442.16153951
Heavy Atom Count:31
Complexity:497

Purity/Quality:

99% ^*data from raw suppliers

1,4-Bis(diphenylphosphino)butane monooxide 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 22-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(CCCCP(=O)(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 4-Diphenylphosphorylbutyl(diphenyl)phosphane

There total 4 articles about 4-Diphenylphosphorylbutyl(diphenyl)phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: 85686-00-6
diphenylphosphino(diphenylphosphonyl)butane

Guidance literature:: With palladium diacetate; sodium hydroxide; ethylene dibromide; In dichloromethane; for 72h; Heating;
DOI:10.1021/ja990841+

Reference yield: 71.0%

: 4151-27-3
1,4-bis(diphenylphosphinyl)butane

: 85686-00-6
diphenylphosphino(diphenylphosphonyl)butane

Guidance literature:: 1,4-bis(diphenylphosphinyl)butane; With trifluoromethylsulfonic anhydride; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

With n-pentanethiol; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 16h; Inert atmosphere;
DOI:10.1039/b807695b

Reference yield:

: C₁₈H₁₇NO₂

: 7688-25-7
1,4-di(diphenylphosphino)-butane

: C₁₈H₁₇NO

: 85686-00-6
diphenylphosphino(diphenylphosphonyl)butane

: 4151-27-3
1,4-bis(diphenylphosphinyl)butane

Guidance literature:: With 3,5-di-tert-butyl-o-benzoquinone; molybdenum hexacarbonyl; In toluene; at 120 ℃; for 18h; regioselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1002/anie.202103429