Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide

Base Information

• Chemical Name: Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide
• CAS No.: 4151-27-3
• Molecular Formula: C28H28O2P2
• Molecular Weight: 458.477
• Mol file: 4151-27-3.mol

Synonyms:Tetra-P-phenyl-P,P'-butanediyl-bis-phosphine oxide;bis-(diphenylphosphino)butane-P,P'-dioxide;P,P'-tetramethylene-bis(diphenylphosphine oxide);tetraphenyltetramethylenediphosphine dioxide;1,4-tetramethylenebis(diphenylphosphine oxide);tetramethylenebis(diphenylphosphine) dioxide;

Chemical Property of Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide

Chemical Property:

• PSA: 53.76000
• LogP: 5.79480

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide

There total 18 articles about Diphenyl[4-(diphenylphosphinyl)butyl]phosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,4-dibromo-butane (110-52-1) + Diphenylphosphine oxide (4559-70-0) → 1,4-bis(diphenylphosphinyl)butane (4151-27-3)

Guidance literature:

With sodium hydroxide; In benzene; for 5h;

Reference yield: 95.0%

1,4-di(diphenylphosphino)-butane (7688-25-7) → 1,4-bis(diphenylphosphinyl)butane (4151-27-3)

Guidance literature:

With dihydrogen peroxide; In dichloromethane; water; for 0.0833333h;

DOI:10.1039/b807695b

Reference yield: 48.0%

Butane-1,4-diol (110-63-4) + phenyl diphenylphosphinite (13360-92-4) → 1,4-bis(diphenylphosphinyl)butane (4151-27-3)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; In neat (no solvent); at 120 ℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube; Green chemistry;

DOI:10.1039/c8gc00931g

upstream raw materials:

1,4-bis(bromomagnesium)butane

Diphenylphosphinic chloride

vinyldiphenylphosphine oxide

tetrachlorure d'octaphenyl-1,1,4,4,9,9,12,12 tetraphosphonia-1,4,9,12 cyclohexadecane

Downstream raw materials:

1,1,6,6-tetraphenyl-1,5-hexadiene

<5,5-Diphenyl-penten-(4)-yl-(1)>-diphenylphosphinoxid

1-chloro-1,4-di(diphenylphosphinyl)butane

(-)-trans-bis-1,2-(diphenylphosphinyl)cyclobutane