Benzeneethanol, b-methylene-, benzoate

Base Information

• Chemical Name: Benzeneethanol, b-methylene-, benzoate
• CAS No.: 86148-32-5
• Molecular Formula: C16H14O2
• Molecular Weight: 238.286
• Mol file: 86148-32-5.mol

Synonyms:

Chemical Property of Benzeneethanol, b-methylene-, benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzeneethanol, b-methylene-, benzoate

There total 1 articles about Benzeneethanol, b-methylene-, benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

iodobenzene (591-50-4) + vinyl benzoate (583-04-0) → cinnamyl benzoate (50555-04-9) + 2-phenyl-2-propen-1-ol benzoate (86148-32-5)

Guidance literature:

With palladium diacetate; silver carbonate; glyoxal bis(N-methyl-N-phenylhydrazone); In toluene; at 90 ℃; for 8h;

DOI:10.1002/ejoc.201101533

Reference yield: 98.0%

carbon monoxide (201230-82-2) + methyl 2-(2-benzamidophenyl)-2-diazoacetate + 2-phenyl-2-propen-1-ol benzoate (86148-32-5) → methyl 1-benzoyl-2-oxo-3-(2-phenylallyl)indoline-3-carboxylate

Guidance literature:

carbon monoxide; methyl 2-(2-benzamidophenyl)-2-diazoacetate; With bis-triphenylphosphine-palladium(II) chloride; potassium phosphate; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene; In toluene; at 20 ℃; under 760.051 Torr; Schlenk technique; Sealed tube;

2-phenyl-2-propen-1-ol benzoate; In toluene; at 60 ℃; for 5h; Sealed tube;

DOI:10.1021/acs.orglett.2c00073

Reference yield: 64.0%

2-phenyl-2-propen-1-ol benzoate (86148-32-5) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 1-phenyl-2-tosylethanone (31378-03-7)

Guidance literature:

With oxygen; copper(II) bis(trifluoromethanesulfonate); In water; acetonitrile; at 65 ℃; for 12h; Inert atmosphere;

DOI:10.1002/cjoc.202000549

upstream raw materials:

iodobenzene

vinyl benzoate

Downstream raw materials:

2,5-diphenyl-hexa-1,5-diene

2-bromo-1-phenyl-2-(toluene-4-sulfonyl)ethanone

2-hydroxy-2-phenylethyl 4-methylphenyl sulfone

(E)-1,5-diphenyl-2-tosylpent-4-en-1-one

Refernces