chlorotris(triphenylarsine)rhodium

Base Information

• Chemical Name: chlorotris(triphenylarsine)rhodium
• CAS No.: 14973-92-3
• Molecular Formula: C54H45 As3 Cl Rh
• Molecular Weight: 1057.07
• Mol file: 14973-92-3.mol

Synonyms:Rhodium,chlorotris(triphenylarsine)- (8CI); Arsine, triphenyl-, rhodium complex;Chlorotris(triphenylarsine)rhodium; Tris(triphenylarsine)rhodium chloride

Chemical Property of chlorotris(triphenylarsine)rhodium

Chemical Property:

• Vapor Pressure: 1.98E-05mmHg at 25°C
• Boiling Point: 373°Cat760mmHg
• Flash Point: 174.6°C
• PSA: 0.00000
• Density: g/cm³
• LogP: 7.63540

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorotris(triphenylarsine)rhodium

There total 2 articles about chlorotris(triphenylarsine)rhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2Rh(2+)*4C2H4*4Cl(1-)={Rh(C2H4)2Cl2}2 + triphenyl-arsane (603-32-7) → Rh(As(C6H5)3)3Cl (14973-92-3)

Guidance literature:

In benzene;

DOI:10.1016/S0022-328X(00)91023-4

Reference yield:

dichlorotetraethylene dirhodium (I), (12081-16-2) + triphenyl-arsane (603-32-7) → Rh(As(C6H5)3)3Cl (14973-92-3)

Guidance literature:

In methanol; diethyl ether; refluxing;

DOI:10.1039/J19660001736

Reference yield: 68.0%

RhCl(AsPh3)3 (14973-92-3) → RhCl(CO)(AsPh3)2 (14877-90-8,16970-35-7)

Guidance literature:

With carbon oxide sulfide; In benzene; byproducts: SAs(C6H5)3; bubbling of COS into soln. (benzene) of Rh-complex (2 h), stirring (2 h), keeping overnight, under N2; addn. of methanol, centrifugation, washing (successively with methanol, ether), drying in vacuo;

upstream raw materials:

dichlorotetraethylene dirhodium (I),

triphenyl-arsane

Downstream raw materials:

RhCl(CO)(AsPh3)2

Refernces