Bis(1,10-phenanthroline)(dipyrido(3,2-a:2',3'-c)phenazine)ruthenium (II)

Base Information

• Chemical Name: Bis(1,10-phenanthroline)(dipyrido(3,2-a:2',3'-c)phenazine)ruthenium (II)
• CAS No.: 92543-42-5
• Molecular Formula: C₄₂H₂₆N₈Ru
• Molecular Weight: 743.792
• Mol file: 92543-42-5.mol

Synonyms:bis(1,10-phenanthroline)(dipyrido(3,2-alpha-2'.3'-C)phenazine)ruthenium (II);BPDP-Ru

Chemical Property of Bis(1,10-phenanthroline)(dipyrido(3,2-a:2',3'-c)phenazine)ruthenium (II)

Chemical Property:

• Boiling Point: 589.1°Cat760mmHg
• Flash Point: 279.3°C
• PSA: 49.06000
• Density: g/cm³
• LogP: 4.67480
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 744.132383
• Heavy Atom Count: 51
• Complexity: 596

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)N=C3C4=C(C5=C(C3=N2)C=CN=C5)N=CC=C4.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.[Ru+2]

Technology Process of Bis(1,10-phenanthroline)(dipyrido(3,2-a:2',3'-c)phenazine)ruthenium (II)

There total 3 articles about Bis(1,10-phenanthroline)(dipyrido(3,2-a:2',3'-c)phenazine)ruthenium (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Ru(1,10-phenanthroline)2Cl2] + dipyridil[3,2-a:2',3'-c]phenazine (19535-47-8) → bis(1,10-phenanthroline)(dipyrido[3,2-a:2',3'-c]phenazine)ruthenium(II) (148409-03-4,148409-04-5,92543-42-5)

Guidance literature:

In ethanol; water; refluxed for more than 3 h;

DOI:10.1021/ja0677564

Reference yield:

[Ru(phen)2(dppz)](PF6)2 → [Ru(phen)2(dppz)](2+) (148409-03-4,148409-04-5,92543-42-5) + [Ru(phen)2(dppz)](2+) (148409-03-4,148409-04-5,92543-42-5)

Guidance literature:

With acetic acid; triethylamine; In methanol; acetonitrile; at 20 ℃; Reagent/catalyst; Resolution of racemate;

DOI:10.1002/chir.22389

Reference yield:

[Ru(phen)2(dppz)](PF6)2 → [Ru(phen)2(dppz)](2+) (148409-03-4,148409-04-5,92543-42-5) + [Ru(phen)2(dppz)](2+) (148409-03-4,148409-04-5,92543-42-5)

Guidance literature:

With acetic acid; triethylamine; In methanol; acetonitrile; at 20 ℃; Reagent/catalyst; Resolution of racemate;

DOI:10.1002/chir.22389

upstream raw materials:

dipyridil[3,2-a:2',3'-c]phenazine

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