2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate

Base Information

Chemical Name:2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate
CAS No.:86838-58-6
Molecular Formula:C11H20O4S
Molecular Weight:248.343
Hs Code.:
DSSTox Substance ID:DTXSID10539119

Synonyms:86838-58-6;2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate;DTXSID10539119

Suppliers and Price of 2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate

Chemical Property:

XLogP3:1.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:2
Exact Mass:248.10823029
Heavy Atom Count:16
Complexity:387

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CC(C(CC1=O)(C)C)OS(=O)(=O)C)C

Technology Process of 2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate

There total 2 articles about 2,2,5,5-Tetramethyl-4-oxocyclohexyl methanesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 95910-60-4
(RS)-4-hydroxy-2,2,5,5-tetramethylcyclohexan-1-one

: 124-63-0
methanesulfonyl chloride

: 86838-58-6
Methanesulfonic acid 2,2,5,5-tetramethyl-4-oxo-cyclohexyl ester

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1016/S0040-4039(00)81855-9

Reference yield:

: 86838-54-2
2,2,5,5-tetramethyl-cyclohexane-1,4-dione

: 86838-58-6
Methanesulfonic acid 2,2,5,5-tetramethyl-4-oxo-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) tAmONa 2.) Diisobutylaluminium hydride / 1.) THF, -20 to 0 deg C 2.) -20 to +20 deg C

2: 97 percent / Et₃N / CH₂Cl₂ / 0.5 h / 0 °C

With sodium tert-pentoxide; diisobutylaluminium hydride; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4039(00)81855-9