PENTAFLUOROPHENYL METHACRYLATE

Base Information

• Chemical Name: PENTAFLUOROPHENYL METHACRYLATE
• CAS No.: 13642-97-2
• Molecular Formula: C10H5F5O2
• Molecular Weight: 252.141
• Hs Code.: 2916140000
• Mol file: 13642-97-2.mol

Synonyms:Methacrylic acid,pentafluorophenyl ester;Pentafluorophenyl-methacrylate;pentafluorophenyl 2-methylpropenoate;2-Propenoic acid,2-methyl-,pentafluorophenyl ester;

Chemical Property of PENTAFLUOROPHENYL METHACRYLATE

Chemical Property:

• Vapor Pressure: 0.0404mmHg at 25°C
• Refractive Index: n20/D1.438
• Boiling Point: 239.3°Cat760mmHg
• Flash Point: 98.3°C
• PSA: 26.30000
• Density: 1.432g/cm³
• LogP: 2.86360
• Storage Temp.: Keep Cold

Purity/Quality:

97% ^*data from raw suppliers

Pentafluorophenyl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: The PFP unit acts as an activated ester for coupling (esterification/amidation) reactions. This is also a monomer for low refractive index polymers (n ~1.40).

Technology Process of PENTAFLUOROPHENYL METHACRYLATE

There total 3 articles about PENTAFLUOROPHENYL METHACRYLATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.52%

2,3,4,5,6-pentafluorophenol (771-61-9) + Methacryloyl chloride (920-46-7,26937-45-1) → pentafluorophenyl 2-methylpropenoate (13642-97-2)

Guidance literature:

With 2,6-dimethylpyridine; In dichloromethane; at 0 - 20 ℃;

Reference yield: 85.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 2,3,4,5,6-pentafluorophenol (771-61-9) → pentafluorophenyl 2-methylpropenoate (13642-97-2)

Guidance literature:

poly(methacrylic acid); With dmap; In dichloromethane; Cooling with ice; Inert atmosphere;

2,3,4,5,6-pentafluorophenol; With dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1002/chem.201703151

Reference yield:

→ pentafluorophenyl 2-methylpropenoate (13642-97-2)

Guidance literature:

upstream raw materials:

2,3,4,5,6-pentafluorophenol

Methacryloyl chloride

poly(methacrylic acid)

Downstream raw materials:

3,3-dimethyl-1,4-diphenyl-azetidin-2-one