1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)-

Base Information

Chemical Name:1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)-
CAS No.:876292-95-4
Molecular Formula:C19H31BO2
Molecular Weight:302.265
Hs Code.:

Synonyms:

Suppliers and Price of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)-

There total 3 articles about 1,3,2-Dioxaborinane, 5,5-dimethyl-2-(4-octylphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 4-octylphenyl trifluoromethanesulfonate

: 201733-56-4
2-(5,5-dimethyl-1,3,2-dioxaborinan-2-yl)-5,5-dimethyl-1,3,2-dioxaborinane

: 876292-95-4
2,2-dimethyl-1,3-propanediol 4-octylphenylboronate

Guidance literature:: With CH₃COOK; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In dimethylsulfoxide; addn. of palladium compd., potassium acetate and diboron compd. to soln.of triflate deriv. in dry DMSO under N2, stirring at 80°C for 4 h; extn. (ethyl acetate), washing with brine, drying over MgSO4, concg. in vac., chromy. (SiO2, petroleum ether/diethyl ether (95:5)), NMR and MS;
DOI:10.1039/c004218h

Reference yield:

: 51554-93-9
1-bromo-4-octylbenzene

: 876292-95-4
2,2-dimethyl-1,3-propanediol 4-octylphenylboronate

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: B(OMe)3 / tetrahydrofuran; hexane / -78 - 20 °C

1.3: aq. HCl / tetrahydrofuran; hexane / pH 5 - 7

2.1: 3.66 g / CH₂Cl₂ / 20 °C

With n-butyllithium; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/jo060768n