1-Nonanethiol

Base Information

• Chemical Name: 1-Nonanethiol
• CAS No.: 1455-21-6
• Molecular Formula: C9H20 S
• Molecular Weight: 160.324
• Hs Code.: 29309090
• European Community (EC) Number: 215-936-7
• ICSC Number: 1620
• NSC Number: 5563
• UN Number: 1228,3334
• UNII: 39LG2ETV2J
• DSSTox Substance ID: DTXSID9061704
• Nikkaji Number: J43.501E
• Wikidata: Q20966422
• Mol file: 1455-21-6.mol

Synonyms:1-nonanethiol

Chemical Property of 1-Nonanethiol

Chemical Property:

• Appearance/Colour: Clear, yellow liquid with a stench.
• Vapor Pressure: 0.172mmHg at 25°C
• Melting Point: -20.1°C
• Refractive Index: n20/D 1.455(lit.)
• Boiling Point: 220 ºC
• PKA: 10.52±0.10(Predicted)
• Flash Point: 174 ºF
• PSA: 38.80000
• Density: 0.842
• LogP: 3.66680
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)
• XLogP3: 5.2
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 7
• Exact Mass: 160.12857181
• Heavy Atom Count: 10
• Complexity: 52.7
• Transport DOT Label: Flammable Liquid Poison

Purity/Quality:

98%,99%, ^*data from raw suppliers

1-Nonanethiol ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 23-26-28

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Thiols
• Canonical SMILES: CCCCCCCCCS
• Inhalation Risk: No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20 °C.
• Effects of Short Term Exposure: The substance is irritating to the eyes, respiratory tract and skin.
• Uses: 1-Nonanethiol is a germination stimulator. It stimulates the germination of uredospores of Puccinia graminis tritici. 1-Nonanethiol is mainly used to form self-organized monolayers on gold, mercury, silver and platinum surfaces. These monolayers functionalize the surface atoms and improve the surface property of the composite.

Technology Process of 1-Nonanethiol

There total 12 articles about 1-Nonanethiol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

3-(2-aminophenyl)-2-(nonylthio)-4-methylthiazol-3-ium iodide (1210046-95-9) → 3-methyl-thiazolo[3,2-a]benzimidazolium iodide + Nonane-1-thiol (1455-21-6)

Guidance literature:

With methanol; for 12h; Reflux;

DOI:10.3390/molecules14114634

Reference yield: 14.9%

nonyl alcohol (143-08-8) → non-1-ene (124-11-8) + Nonane-1-thiol (1455-21-6) + dinonylsulfane (929-98-6)

Guidance literature:

With P, S; at 170 - 200 ℃; for 6.5h; Product distribution;

Reference yield:

nonyl-(1,2,3,4-tetrahydro-[1]naphthyl)-sulfide (109937-65-7) → naphthalene (91-20-3,71998-51-1,72931-45-4) + tetralin (119-64-2) + nonane (111-84-2) + Nonane-1-thiol (1455-21-6)

Guidance literature:

at 300 ℃;

upstream raw materials:

1-Bromononane

thiourea

nonyl alcohol

dinonylsulfane

Downstream raw materials:

n-Nonylthiostearat

n-Nonylthiopalmitat

1,2-Bis-nonylmercapto-ethan

D-Glucose-S,S-dinonylacetal

Refernces

• 1、 Mehdid, Mohammed Amine,Djafri, Ayada,Roussel, Christian,Andreoli, Federico. "3-(2-aminophenyl)-4-methyl-1,3-thiazole-2(3H)-thione as an ecofriendly sulphur transfer agent to prepare alkanethiols in high yield and high purity". experimental part. p. 4634 - 4643. Retrieved 2010/04/06.
• 2、 -. "Antimicrobial composition and method containing N-(3,5-dihalophenyl)-imide compounds". . . Retrieved 2008/06/13.