Sucrose 2,3,3',4',6-pentaacetate

Base Information Edit

Chemical Name:Sucrose 2,3,3',4',6-pentaacetate
CAS No.:35867-25-5
Molecular Formula:C22H32O16
Molecular Weight:552.486
Hs Code.:
European Community (EC) Number:252-768-3
UNII:98KX3NW9C5
DSSTox Substance ID:DTXSID80957285
Nikkaji Number:J319.551A
Wikidata:Q27272120
Mol file:35867-25-5.mol

Synonyms:35867-25-5;Sucrose 2,3,3',4',6-pentaacetate;UNII-98KX3NW9C5;98KX3NW9C5;EINECS 252-768-3;2,3,3',4',6-Penta-O-acetylsucrose;2,3,6,3',4'-Penta-O-acetylsucrose;[(2R,3R,4S,5R,6R)-4,5-diacetyloxy-6-[(2S,3S,4R,5R)-3,4-diacetyloxy-2,5-bis(hydroxymethyl)oxolan-2-yl]oxy-3-hydroxyoxan-2-yl]methyl acetate;6-PAS;DTXSID80957285;AHLIHMGXFJRKSY-ZQNATQRZSA-N;(2R,3R,4S,5R,6R)-6-(acetoxymethyl)-2-(((2S,3S,4R,5R)-3,4-diacetoxy-2,5-bis(hydroxymethyl)tetrahydrofuran-2-yl)oxy)-5-hydroxytetrahydro-2H-pyran-3,4-diyl diacetate;2,3,6,3',4'-PENTAACETYLSUCROSE;SUCROSE, 2,3,3',4',6-PENTAACETATE;Q27272120;3,4-di-O-acetylhex-2-ulofuranosyl 2,3,6-tri-O-acetylhexopyranoside;.ALPHA.-D-GLUCOPYRANOSIDE, 3,4-DI-O-ACETYL-.BETA.-D-FRUCTOFURANOSYL, 2,3,6-TRIACETATE

Suppliers and Price of Sucrose 2,3,3',4',6-pentaacetate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
2,3,3'',4'',6-Penta-O-acetylsucrose
250mg
$ 960.00

Medical Isotopes, Inc.
2,3,3??,4??,6-Penta-O-acetylsucrose
100 mg
$ 625.00

Biosynth Carbosynth
3,4,2',3',6'-Penta-O-acetylsucrose
25 mg
$ 90.00

Biosynth Carbosynth
3,4,2',3',6'-Penta-O-acetylsucrose
500 mg
$ 950.00

Biosynth Carbosynth
3,4,2',3',6'-Penta-O-acetylsucrose
100 mg
$ 275.00

Biosynth Carbosynth
3,4,2',3',6'-Penta-O-acetylsucrose
50 mg
$ 175.00

Biosynth Carbosynth
3,4,2',3',6'-Penta-O-acetylsucrose
250 mg
$ 550.00

AK Scientific
Sucrose2,3,3',4',6-pentaacetate
100mg
$ 421.00

AK Scientific
Sucrose2,3,3',4',6-pentaacetate
25mg
$ 171.00

Total 6 raw suppliers

Chemical Property of Sucrose 2,3,3',4',6-pentaacetate Edit

Chemical Property:

PSA：219.88000
LogP:-2.54160
Solubility.:Chloroform, Dichloromethane, Ethyl Acetate
XLogP3:-2.7
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:16
Rotatable Bond Count:15
Exact Mass:552.16903493
Heavy Atom Count:38
Complexity:891

Purity/Quality:

99% ^*data from raw suppliers

2,3,3'',4'',6-Penta-O-acetylsucrose ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)OC2(C(C(C(O2)CO)OC(=O)C)OC(=O)C)CO)OC(=O)C)OC(=O)C)O
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)O[C@]2([C@H]([C@@H]([C@H](O2)CO)OC(=O)C)OC(=O)C)CO)OC(=O)C)OC(=O)C)O
Uses 2,3,4,3',4'-Penta-O-acetylsucrose is used in the synthesis of Sucralose sweetener.

Technology Process of Sucrose 2,3,3',4',6-pentaacetate

There total 7 articles about Sucrose 2,3,3',4',6-pentaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 34382-02-0
2,3,4,3',4'-penta-O-acetylsucrose

: 35867-25-5
2,3,6,3',4'-pentaacetyl sucrose (6-PAS)

Guidance literature:: With tert-butylamine; In ethyl acetate; at 45 - 50 ℃; for 6h;

Reference yield:

: 35867-26-6,75800-72-5
2,3,4,3',4'-penta-O-acetyl-6,1',6'-tri-O-tritylsucrose

: 35867-25-5
2,3,6,3',4'-pentaacetyl sucrose (6-PAS)

Guidance literature:: 2,3,4,3',4'-penta-O-acetyl-6,1',6'-tri-O-tritylsucrose; With hydrogen; benzyl chloride; palladium 10% on activated carbon; In 1,2-dichloro-ethane; at 27 ℃; under 7355.72 Torr;

With acetic acid; In 4-methyl-2-pentanone; at 100 - 110 ℃; for 3h; Product distribution / selectivity;